ACETAMIPRID plus NOVALURON

1_Trade_NameManufacturerForm
CORMORAN INSECTICIDEADAMA AUSTRALIA PTY LIMITEDEMULSIFIABLE CONCENTRATE

4. ACTIVE INGREDIENTS: ACETAMIPRID 80 g/L + NOVALURON 100g/L

5. COST: $112.24 per L or kg.

6. CHEMICAL GROUP: 4A,15.

7. RELATED PESTICIDES:

ACETAMIPRID 80 g/L + NOVALURON 100g/L

8. GENERAL DESCRIPTION:

An insecticide used mainly for Apple Dimpling Bug, Codling Moth, Light Brown Apple Moth, Longtailed Mealybug, Plague Thrips and Tuber Mealybug control in apples and pears.

9. APPLICATION METHODS AND TIPS:

Best results in fine mild weather when insects are active.
Avoid spraying during flowering. Toxic to bees.
30 m downwid buffer for livestock and pasture. 200 m downwid buffer for aquatic areas.
Ensure thorough coverage.

10. ADJUVANTS, WETTERS, OILS:

11. EQUIPMENT:

High volume sprayers are normally used.

12. SPRAYER WASH OUT AND DECONTAMINATION:

13. WATER OR CARRIER DATA:

High volumes of at least 1000 L/ha are generally used to ensure thorough coverage.

14. WEATHER:

Wind speed must be between 3 and 20 kph.
Best results in fine weather.

15. RAINFASTNESS:

hours

16. SOIL:

17. PLANT HEALTH and OTHER EFFECTS:

18. WITHHOLDING PERIODS:

Apple: Harvest - 70 days. Grazing - Do not graze.
Pears: Harvest - 35 days. Grazing - Do not graze.
Apple: Harvest - 70 days. Grazing - Do not graze.
Pears: Harvest - 35 days. Grazing - Do not graze.

19. PLANT BACK PERIODS or RECROPPING INTERVALS:

20. MODE OF ACTION:

21. PESTICIDE RESISTANCE:

Some species may be resistant or develop resistance with continued application. Rotate with products from alternative groups.

22. TOXICITY:

Poison schedule - S0
Summary:Poisonous if swallowed. May irritate the eyes. Avoid contact with eyes. Avoid breathing vapour or spray mist.
Details:
Poison schedule - S6
Mammalian toxicity - Moderate.
Acute oral LD50 - LD50(rat): 580 mg/kg
LD50(mouse): 404 mg/kg(male), 335 mg/kg(female), [For comparison table salt is 3000 mg/kg]
Acute dermal LD50(rat): >2000 mg/kg.
Skin - Not irritating. Not sensiitising
Eye - Moderate irritation.
Vapour inhalation - EC50(rat): 6.54 mg/L (4 hr).
Chronic oral toxicity (2 years) (active ingredient) NOEL(rat): 1.1 mg/kg/day.
Not carcinogenic, mutagenic or teratogenic (i.e. Does not cause cancer or reproductive problems).
Acceptable Daily Intake (ADI) - Novaluron 0.01 mg/k/day. NOEL 1.1 mg/kg/day.
N-methyl-2-pyrrolidone is a SWA Class 2 Reproductive risk, may cause harm to the unborn child.

23. TOXICITY SYMPTOMS:

Symptoms may include headache, irritation of nose and throat and increased secretion of mucous in the nose and throat, skin rash or inflammation, itchiness and reddening of skin exposed.
Stinging, reddening and watering of the eyes may occur if in the eyes.

24. FIRST AID:

If SWALLOWED - Do NOT induce vomiting. Wash mouth with water and contact a Poisons Information Centre, or call a doctor.
Never give anything by mouth to an unconscious person.
If in EYES -Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 15 minutes or until the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the unaffected eye or onto the face. Obtain medical attention immediately. Take special care if exposed person is wearing
contact lenses.
If on SKIN - Wash gently and thoroughly with warm water for 10-20 minutes or until product is removed. Under running water, remove ontaminated clothing, shoes and leather goods (e.g. watchbands and belts) and completely decontaminate them before reuse or discard. If irritation persists, repeat flushing and seek medical attention.
If INHALED - If symptoms of poisoning become evident, contact a Poisons Information Centre, or call a doctor at once. Remove source of contamination or move victim to fresh air. If breathing is difficult, oxygen may be beneficial if administered by trained personnel, preferably on a doctor's advice. DO NOT allow victim to move about
unnecessarily. Symptoms of pulmonary oedema can be delayed up to 48 hours after exposure.
If patient has symptoms or is concerned contact a doctor immediately.
Advice to doctor - Treat symptomatically. No specific antidote known.
Call Poisons Information Centre on 13 11 26

25. PROTECTIVE CLOTHING:

Safety goggles and face shield.
Elbow length PVC gl;oves.
Cotton overalls and washable hat.
Boots.

26 RE ENTRY PERIODS and OTHER SAFETY ISSUES:

After spray has dried

27. PROPERTIES:

Product appearance - Brown liquid. Characteristic odour.
Product Flammability - Not flammable. C1 Combustible.
Flash point - >92°C (Cleveland open cup)
Half life in water - Acetamiprid Water DT50 3.6-5.8 days
Water solubility at 25 C. - emulsifiable
Oil solubility -
Octanol:Water ratio at 25 C. - Log Pow Acetamipirid = 0.8, Novaluron = 4.3.
Acetamipirid Koc 71.1-138.4
Vapour density - 3.42 (N-methyl-2-pyrrolidone)
2.7 (dimethyl sulfoxide)
Dissociation constant - pKa.
Melting point - C.
Boiling point - 202°C (N-methyl-2-pyrrolidone)
189°C (dimethyl sulfoxide)
Molecular weight -
Density - 1.107 g/cm3 (at 20°C)
pH - 5-7
Fire - Use fine water spray or extinguishers. May emit toxic fumes in fire.

28. ENVIRONMENTAL FATE:

Summary - Toxic to aquatic invertebrates and bees
Birds - toxicity.Acetamiprid: LD50 (Oral), Mallard, 98mg/kg
Fish - Low toxicity. Carp LC50 (96 hr): 386 mg/L
Invertebrates - High toxicity. Daphnia; Novaluron EC50 (48 hr): 4.22. mg/L. Acetamiprid EC50 (48 hr): 557 mg/L
Bees - Hgh toxicity. Residue may remain toxic to bees ofr several days after spraying. Acetamiprid: Oral LD50 14.5ìg/bee
Algae - Low toxicity. EbC50 (72 hr): 560 mg/L
It has a half life in water: Acetamiprid Water DT50 3.6-5.8 days
It has a half life in soil: Acetamiprid Soil DT50 2.9 days and
Novaluron Soil DT50 68-76 days.
It has an EPA classification for soil mobility that ranges from
Ground water contamination Unlikely.
Accumulation in milk and tissues.
Product is biodegradable. It will not accumulate in the soil or water or cause long term problems.
Not bioaccumulative.

29. COMPATIBILITY:

See HerbiGuide for compatibility with other herbicides, insecticides and fungicides.
See HerbiGuide for a full list of pesticide compatibilities.

30. REGISTERED CROPS, INSECTS and DISEASES.

See HerbiGuide Species Solutions Tab for registered uses.

31. GOVERNMENT AND REGULATORY INFORMATION:

Dangerous Goods Class - Not a dangerous good for ground transport. Class 9 for sea and air transport
Hazchem Code - NA
Classified as: Xi, Irritating. T, Toxic. N, Dangerous to the environment.
Hazardous according to the criteria of SWA.
Packaging Group - NA
Initial Emergency Response Guide IERG -
UN Number - 3082.
CAS Number: Acetamiprid 135410-20-7 80g/L
Novaluron 116714-46-6 100g/L
N-Methyl-2-pyrrolidone 872-50-4
SWA Classification and phrases
Risk Phrases: R43, R61, R66, R20/22, R36/37/38, R50/53. May cause sensitisation by skin contact. May cause harm to the unborn child. Repeated exposure may cause skin dryness or cracking. Harmful by inhalation and if swallowed. Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms, may cause long-term adverse effects to the aquatic environment.
Safety Phrases: S20, S23, S28, S38, S51, S61, S24/25, S36/37/39. When using, do not eat or drink. Do not breathe vapours or spray mist. After contact with skin, wash immediately with plenty of soap and water. In case of insufficient ventilation, wear suitable respiratory equipment. Use only in well ventilated areas. Avoid release to the environment. Refer to special instructions/Safety Data Sheets. Avoid contact with skin and eyes. Wear suitable protective clothing, gloves and eye/face protection
SWA exposure limits: N-Methyl-2-pyrrolidone WA 103(g/m3. STEL309 mg/m3.

32. References:

Label 70152/62630, SDS Cormoran march 2015

Acknowledgments:

Collated by HerbiGuide. Phone 08 98444064 or www.HerbiGuide.com.au for more information.