Acetamiprid plus Emamectin

1_Trade_NameManufacturerForm
SKOPE INSECTICIDEADAMA AUSTRALIA PTY LIMITEDDISPERSIBLE CONCENTRATE

4. ACTIVE INGREDIENTS: Acetamiprid 218g/L + Emamectin 32.5g/L

5. COST: $132.00 per L or kg.

6. CHEMICAL GROUP: 4A,6.

7. RELATED PESTICIDES:

Acetamiprid 218g/L + Emamectin 32.5g/L

8. GENERAL DESCRIPTION:

An insecticide used mainly for ahipd, mirid, vegetable bug, heliothis and silver leaf white fly control in cotton.

9. APPLICATION METHODS AND TIPS:

Ensure thorough coverage.
To be effective, insects must eat treated foliage.
Do not apply more than two applications per season.

10. ADJUVANTS, WETTERS, OILS:

Adding a non-ionic wetting agent may improve control.

11. EQUIPMENT:

Use medium droplet size or coarser to reduce drift unless using airblast sprayers.
High volume sprayer are preferred.

12. SPRAYER WASH OUT AND DECONTAMINATION:

13. WATER OR CARRIER DATA:

80-100 L/ha for ground applications.
20-30 L/ha for aerial applications.

14. WEATHER:

Buffer zones of 10 metres for aquatic areas for ground sprays.
Spray when wind in 3-20 kph.
Avoid spraying during temperatures inversions to reduce the risk of drift.
Apply when wind speed is 3-20 kph.

15. RAINFASTNESS:

16. SOIL:

17. PLANT HEALTH and OTHER EFFECTS:

18. WITHHOLDING PERIODS:

Cotton: Harvest - 7 days. Grazing - Do not graze.
Don't feed cotton trash to animals or poultry.
Cotton: Harvest - 7 days. Grazing - Do not graze.
Don't feed cotton trash to animals or poultry.

19. PLANT BACK PERIODS or RECROPPING INTERVALS:

20. MODE OF ACTION:

Group 11, the Quinone outside Inhibitor (QoI) group of fungicides

21. PESTICIDE RESISTANCE:

Some species may be resistant or develop resistance with continued application. Rotate with products from alternative groups.

22. TOXICITY:

Poison schedule - S6
Summary:Poisonous if swallowed. Will irritate the eyes. Avoid contact with eyes. Avoid breathing vapour or spray mist.
Details:
Poison schedule - S6
Mammalian toxicity - Moderate.
Acute oral LD50 - LD50(rat): 300-2000 mg/kg
LD50(mouse): 404 mg/kg(male), 335 mg/kg(female), [For comparison table salt is 3000 mg/kg]
Acute dermal LD50(rat): >2000 mg/kg.
Skin - Not irritating. Not sensiitising
Eye - Slight irritation.
Vapour inhalation - EC50(rat): 6.54 mg/L (4 hr).
Chronic oral toxicity (2 years) (active ingredient) NOEL(rat): 7.1 mg/kg/day (male)C8.8 mg/kg/day (female)C
Not carcinogenic, mutagenic or teratogenic (i.e. Does not cause cancer or reproductive problems).
Acceptable Daily Intake (ADI) -

23. TOXICITY SYMPTOMS:

24. FIRST AID:

If SWALLOWED - Do not induce vomiting unless directed to do so by medicinal personnel. Never give anything by mouth to an unconscious
person. Rinse mouth with water. Call a physician.
If in EYES - Irrigate for 15 minutes with plenty of water.
If on SKIN - Rinse with plenty of water, remove contaminated clothing, wash with soap and water.
If INHALED - Remove patient to fresh air.
If patient has symptoms or is concerned contact a doctor immediately.
Advice to doctor - Treat symptomatically. No specific antidote known.
Call Poisons Information Centre on 13 11 26

25. PROTECTIVE CLOTHING:

Safety goggles and face shield.
Elbow length PVC gl;oves.
Cotton overalls and washable hat.
Boots.

26 RE ENTRY PERIODS and OTHER SAFETY ISSUES:

After spray has dried

27. PROPERTIES:

Product appearance - Clear light green liquid. Sweet odour
Shelf Life -
Product Flammability - Combustible liquid.
Flash point - 102°C (Cleveland open cup)
Half life in water - DT50 of 3.6-5.8 days (Acetamiprid).
Water solubility at 25 C. - ppm at pH
Oil solubility -
Octanol:Water ratio at 25 C. - Log POW 0.8 a 25 C (Acetamiprid).
Log POW 2.7 (Emamectin).
Koc 71.1-138.4 (Acetamiprid).
Vapour density - 3.42 (N-methyl-2-pyrrolidone), 2.7 (dimethyl sulfoxide)
Dissociation constant - pKa.
Melting point - C.
Boiling point - 202°C (N-methyl-2-pyrrolidone), 189°C (dimethyl sulfoxide)
Molecular weight -
Density - 1.1-1.2 g/cm3 (at 25°C)
Viscosity - 46.2 mm2/sec at 40 C
pH - 4.5-5.2 (1% solution)
Fire - Use fine water spray or extinguishers. May emit toxic fumes in fire.

28. ENVIRONMENTAL FATE:

Summary - Very toxic to aquatic life.
Birds - toxicity. LD50 98 mg/kg Mallard (Acetamiprid)
Fish - Toxicit. Rainbow trout LC50 (96 hr): 9.99 mg/L
Invertebrates - Toxic. Daphnia; EC50 (48 hr): 0.0654 mg/L
Bees - High toxicity. LD50 14.5 ug/bee (Acetamiprid).
Residues remain toxic to bees for 11 days
Algae - Low toxicity. EbC50 (72 hr): 315 mg/L
It has a half life in soil with a DT50 of 2.9 days (Acetamiprid).
It has a half life in water with a DT50 of 3.6-5.8 days (Acetamiprid).
It has an EPA classification for soil mobility that ranges from
Ground water contamination unlikely.
Accumulation in milk and tissues.
Not readily biodegradable (as active ingredient).
Not bioaccumulative.

29. COMPATIBILITY:

See HerbiGuide for compatibility with other herbicides, insecticides and fungicides.
See HerbiGuide for a full list of pesticide compatibilities.

30. REGISTERED CROPS, INSECTS and DISEASES.

See HerbiGuide Species Solutions Tab for registered uses.

31. GOVERNMENT AND REGULATORY INFORMATION:

Dangerous Goods Class - Calss 9 Miscelaneaous dangerous good for sea and air travel.
Hazchem Code - 3Z
Packaging Group - III
Initial Emergency Response Guide IERG -
UN Number - 3082
CAS Number - Acetamiprid 135410-20-7
Emamectin 155569-91-8
NOHSC Classification and phrases -
Risk Phrases: R22 Harmful if swallowed
R52 Harmful to aquatic organisms
R53 May cause long-term adverse effects in the aquatic
environment
Safety Phrases: S2 Keep out of reach of children
S46 If swallowed, seek medical advice immediately and show this
container or label.
S61 Avoid release to the environment. Refer to special
instructions/Material Safety Data Sheets.
S20, S23, S29, S35, S61, S64,
Keep records.

32. References:

69787/61735

Acknowledgments:

Collated by HerbiGuide. Phone 08 98444064 or www.HerbiGuide.com.au for more information.