Benzovindiflupyr plus Propiconazole

1_Trade_NameManufacturerForm
ELATUS ACE SOLATENOL brand FungicideSYNGENTA AUSTRALIA PTY LTDEMULSIFIABLE CONCENTRATE

4. ACTIVE INGREDIENTS: Benzovindiflupyr 40 g/L + Propiconazole 250g/L

5. COST: $42.90 per L or kg.

6. CHEMICAL GROUP: 7,3.

7. RELATED PESTICIDES:

Benzovindiflupyr 40 g/L + Propiconazole 250g/L

8. GENERAL DESCRIPTION:

An agricultural fungicide for the control of leaf diseases in cereals.

9. APPLICATION METHODS AND TIPS:

Ensure thorough coverage.
DO NOT apply if rain is expected within 48 hours to avoid runoff.
DO NOT apply after BBCH growth stage 69.
Toxic to beneficial arthropods so not compatible with IPM using these.

10. ADJUVANTS, WETTERS, OILS:

None recommended

11. EQUIPMENT:

Use a medium spray droplet size to reduce the risk of drift.

12. SPRAYER WASH OUT AND DECONTAMINATION:

13. WATER OR CARRIER DATA:

At least 70 L/ha. Use higher rates is using coarser nozzles.

14. WEATHER:

Apply when the wind speed is 3-20kmhr to reduce the risk of drift.
Do not apply during hazardous temperature inversions to reduce the risk of drift.

15. RAINFASTNESS:

1 hour

16. SOIL:

17. PLANT HEALTH and OTHER EFFECTS:

18. WITHHOLDING PERIODS:

Harvest: Not required when used as directed
Grazing: Do not graze or cut for stock food for 10 days after application
Harvest: Not required when used as directed
Grazing: Do not graze or cut for stock food for 10 days after application

19. PLANT BACK PERIODS or RECROPPING INTERVALS:

20. MODE OF ACTION:

Benzovindiflupyr is a member of the SDHI group of fungicides and propiconazole is a member of the DMI group of fungicides.

21. PESTICIDE RESISTANCE:

Some species may be resistant or develop resistance with continued application. Rotate with products from alternative groups.

22. TOXICITY:

Poison schedule - S6
Summary: Very toxic to aquatic life.
Details:
Poison schedule - S
Mammalian toxicity -
PRODUCT
Acute oral LD50 - >2000 mg/kg (rats), [For comparison table salt is 3000 mg/kg]
Acute dermal LD50 - >2000 mg/kg (rabbit).
Skin - Not irritating. Is sensitising.
Eye - Irritating.
Vapour inhalation - LC50 - >2.16 mg/L air (rat).
Chronic oral toxicity NOEL - ppm for two years.
Not carcinogenic, mutagenic or teratogenic (i.e. Does not cause cancer or reproductive problems).
Acceptable Daily Intake (ADI) -

23. TOXICITY SYMPTOMS:

24. FIRST AID:

May be fatal if swallowed and enters airways.
If SWALLOWED - Do not induce vomiting: contains petroleum distillates and/or aromatic solvents. Seek medical advice immediately
If in EYES - Irrigate for 15 minutes with plenty of water. Immediate medical attention is required.
If on SKIN - Rinse with plenty of water, remove contaminated clothing, wash with soap and water. If irritation persists then see a doctor.
If INHALED - Remove patient to fresh air.
If patient has symptoms or is concerned contact a doctor immediately.
Advice to doctor - Treat symptomatically. No specific antidote
Call Poisons Information Centre on 13 11 26

25. PROTECTIVE CLOTHING:

Safety goggles and face shield.
Elbow length PVC gl;oves.
Cotton overalls and washable hat.
Boots.

26 RE ENTRY PERIODS and OTHER SAFETY ISSUES:

27. PROPERTIES:

Product appearance - Yellow-orange liquid.
Shelf Life -
Product Flammability -
Half life in water - days at pH5 and 35 C.
Water solubility at 25 C. - Emulsifiable.
Oil solubility -
Octanol:Water ratio at 25 C. - at pH 5.
Vapour Pressure at 25 C. -
Dissociation constant - pKa.
Melting point - C.
Boiling point -
Molecular weight -
Density - 1.10 g/cm3 (20 °C)
pH - 4 - 8 Concentration: 1 % w/v
Flash point : 104 °C
Auto-ignition temperature : 370 °C

28. ENVIRONMENTAL FATE:

Summary -
Birds - toxicity.
Fish - High toxicity LC50 (Oncorhynchus mykiss (rainbow trout)): 0.179 mg/L Exposure time: 96 h
Invertebrates - High toxicity. EC50 (Daphnia magna (Water flea)): 0.591 mg/l
Exposure time: 48 h
Bees - toxicity.
Algae - ErC50 (Pseudokirchneriella subcapitata (green algae)): 10.7
mg/L Exposure time: 72 h. NOEC (Pseudokirchneriella subcapitata (green algae)): 9.97 mg/L
Arthropods - Toxic to beneficial arthropods. Not compatible with integrated pest management (IPM) programs utilising beneficial arthropods.
It has a half life in soil of .
Not readily biodegradable.
It has an EPA classification for soil mobility that ranges from
Ground water contamination
Accumulation in milk and tissues.
Persistence and degradability
Components:
propiconazole (ISO):
Biodegradability : Result: Not readily biodegradable.
benzovindiflupyr (ISO):
Biodegradability : Result: Not readily biodegradable.
Bioaccumulative potential
Components:
propiconazole (ISO):
Bioaccumulation : Remarks: Medium bioaccumulation potential.
Partition coefficient: noctanol/ water : log Pow: 3.72 (25 °C)
benzovindiflupyr (ISO):
Bioaccumulation : Remarks: Does not bioaccumulate.
Partition coefficient: noctanol/water : log Pow: 4.3 (25 °C)
Mobility in soil
Components:
propiconazole (ISO):
Distribution among environmental compartments
: Remarks: Low to medium mobility in soil.
Stability in soil : Dissipation time: 66 - 170 d
Percentage dissipation: 50 % (DT50)
Remarks: Product is not persistent.
benzovindiflupyr (ISO):
Distribution among environmental compartments
: Remarks: Slightly mobile in soils
This product is not persistent, bioaccumulating and toxic (PBT). It is not
very persistent and very bioaccumulating (vPvB).

29. COMPATIBILITY:

See HerbiGuide for compatibility with other herbicides, insecticides and fungicides.
See HerbiGuide for a full list of pesticide compatibilities.
Compatible with a range of commonly used fungicides, insecticides, herbicides and fertilizers.

30. REGISTERED CROPS, INSECTS and DISEASES.

See HerbiGuide Species Solutions Tab for registered uses.

31. GOVERNMENT AND REGULATORY INFORMATION:

APVMA Numbers: 86310
UN number:
CAS numbers: propiconazole (ISO) 60207-90-1
benzovindiflupyr (ISO) 1072957-71-1
OPP Chemical Code:
Hazchem code:
NOHSC classification:
Land transport: ADG
UN number : UN 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BENZOVINDIFLUPYR AND PROPICONAZOLE)
Class : 9
Packing group : III
Labels : 9
Hazchem Code : 3Z
Remarks : Environmentally Hazardous Substances meeting the
descriptions of UN 3077 or UN 3082 are not subject to the
Australian Code for the Transport of Dangerous Goods
(ADG). This applies when transported by road or rail in
packagings that do not incorporate a receptacle exceeding
500 kg(L) or IBCs per ADG Special Provision AU01.
International Regulations
UNRTDG
UN number : UN 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BENZOVINDIFLUPYR AND PROPICONAZOLE)
Class : 9
Packing group : III
Labels : 9
IATA-DGR
UN/ID No. : UN 3082
Proper shipping name : Environmentally hazardous substance, liquid, n.o.s.
(BENZOVINDIFLUPYR AND PROPICONAZOLE)
Class : 9
Packing group : III
Labels : Class 9 - Miscellaneous dangerous substances and articles
Packing instruction (cargo aircraft): 964
Packing instruction (passenger aircraft): 964
Environmentally hazardous : yes
IMDG-Code
UN number : UN 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BENZOVINDIFLUPYR AND PROPICONAZOLE)
Class : 9
Packing group : III
Labels : 9
EmS Code : F-A, S-F
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
GHS Classification
Acute toxicity (Oral) : Category 4
Serious eye damage/eye irritation : Category 2A
Skin sensitisation : Sub-category 1B
Reproductive toxicity : Category 2
H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H361 Suspected of damaging fertility or the unborn child.
No Spray Zones: 10m for aquatic areas.
Records: Accurate written records are required.

32. References:

Acknowledgments:

Collated by HerbiGuide. Phone 08 98444064 or www.HerbiGuide.com.au for more information.