Boscalid plus Pyraclostrobin

1_Trade_NameManufacturerForm
NUFARM PRISTINE FUNGICIDENUFARM AUSTRALIA LIMITEDWATER DISPERSIBLE GRANULE
PRISTINE FUNGICIDEBASF AUSTRALIA LTD.WATER DISPERSIBLE GRANULE

4. ACTIVE INGREDIENTS: Boscalid 252g/kg + Pyraclostrobin

5. COST: $182.60 per L or kg.

6. CHEMICAL GROUP: 7,11.

7. RELATED PESTICIDES:

Boscalid 200g/L + kresoxim-methyl 100 g/L
Boscalid 252g/kg + Pyraclostrobin
Fluopyram 250g/L + trifloxystrobin 250g/L
Penflufen 154g/L + trifloxystrobin 154g/L

8. GENERAL DESCRIPTION:

An agricultural fungicide for control of alternaria, botrytis, sclerotinia and venturia(black sot) in various crops and grapes.
It contains an oxathiin and strobilurin fungicide. It is toxic to many aquatic organisms.

9. APPLICATION METHODS AND TIPS:

Ensure thorough coverage.

10. ADJUVANTS, WETTERS, OILS:

A weting agent may be useful for low volume applications or on hard to wet leaves.

11. EQUIPMENT:

High volume sprayer or concentrate sprayer applying more than 250 L/ha water.

12. SPRAYER WASH OUT AND DECONTAMINATION:

13. WATER OR CARRIER DATA:

>250 L/ha water

14. WEATHER:

15. RAINFASTNESS:

16. SOIL:

17. PLANT HEALTH and OTHER EFFECTS:

Good crop safety.

18. WITHHOLDING PERIODS:

Apples - 14 days - harvest - 28 days.
Grazing - Don't graze treated areas.
Export slaughter interval - 7 days.
Apples - 14 days - harvest - 28 days.
Grazing - Don't graze treated areas.
Export slaughter interval - 7 days.

19. PLANT BACK PERIODS or RECROPPING INTERVALS:

20. MODE OF ACTION:

Group 7, oxathiin or pyridine carboxamides family. Group 11 fungicide. Group G and K fungicide

21. PESTICIDE RESISTANCE:

Some species may be resistant or develop resistance with continued application. Rotate with products from alternative groups.

22. TOXICITY:

Poison schedule - S5
Summary: Low toxicity.
Details:
Poison schedule - S0. Exempt.
Mammalian toxicity -
Acute oral LD50 - >2000 mg/kg (rats), [For comparison table salt is 3000 mg/kg]
Acute dermal LD50 - >2000 mg/kg (rabbit).
Skin - Not irritating. Not sensitising.
Eye - Slightly Irrtiating
Vapour inhalation - LC50 - >4 mg/L air (rat).
Chronic oral toxicity NOEL - ppm for two years.
Not mutagenic or teratogenic (i.e. does not cause cancer or reproductive problems).
Acceptable Daily Intake (ADI) - 0.06 mg/kg/day
NOEL - 6 mg/kg/day

23. TOXICITY SYMPTOMS:

No specific symptoms.

24. FIRST AID:

If SWALLOWED - Rinse mouth with water and give a glass of water to drink. Never give anything to drink to an unconscious person.
If in EYES - Irrigate for 15 minutes with plenty of water.
If on SKIN - Rinse with plenty of water, remove contaminated clothing, wash with soap and water.
If INHALED - Remove patient to fresh air.
If patient has symptoms or is concerned contact a doctor immediately.
Advice to doctor - Treat symptomatically.
Call Poisons Information Centre on 13 11 26

25. PROTECTIVE CLOTHING:

Safety goggles and face shield.
Elbow length PVC gl;oves.
Cotton overalls and washable hat.
Boots.

26 RE ENTRY PERIODS and OTHER SAFETY ISSUES:

Wear protective clothing if working in sprayed area before the spray has dried.

27. PROPERTIES:

Product appearance - Solid brown granules and almost odourless.
Shelf Life - Several years.
Product Flammability - Not flammable. Autoignition ~ 348 C
Half life in water - days at pH5 and 35 C.
Water solubility at 25 C. - 4.6 ppm at pH. Disperses in water.
Oil solubility -
Octanol:Water ratio at 25 C. - at pH 5.
Vapour Pressure - 0.00072 mPa (boscalid), 0.000026 mPa (pyraclostrobin)
Dissociation constant - pKa.
Melting point - C.
Boiling point -
Molecular weight -
Density - 464 kg/m3
pH - 6.5.

28. ENVIRONMENTAL FATE:

Summary - Toxic to some aquatic organisms.
Birds - Not toxic. LD50 >2000 mg/kg, bobwhite quail
Fish - High toxicity LC50 2.7 mg/L, 96 hours, rainbow trout, boscalid. LC50 0.006 mg/L, 96 hours, rainbow trout, pyraclostrobin.
Invertebrates - Low toxicity. LC50 50 mg/L, 48 hours, Daphnia magna. LC50 5.33 mg/L, 48 hours, boscalid. LC50 0.016 mg/L, 48 hours, pyraclostrobin.
Bees - Not toxic.
It has a half life in soil of 108 - 365 days. Not readily biodegradable.
It has an EPA classification for soil mobility that ranges from
Ground water contamination - Severe marine polllutant.
Accumulation in milk and tissues.

29. COMPATIBILITY:

See HerbiGuide for compatibility with other herbicides, insecticides and fungicides.
See HerbiGuide for a full list of pesticide compatibilities.

30. REGISTERED CROPS, INSECTS and DISEASES.

See HerbiGuide Species Solutions Tab for registered uses.

31. GOVERNMENT AND REGULATORY INFORMATION:

Classified as hazardous.
Dangerous Goods Class - Non dangerous.
Hazchem Code - 2Z.
Packaging Group - III. Class 9.
ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S. (CONTAINS PYRACLOSTROBIN)
Marine pollutant.
Initial Emergency Response Guide IERG -
UN Number - 3077
NOHSC Classification and phrases - Hazardous.
R22 Harmful of swallowed.
S13 Keep away from food, drink and animal feeding stuffs.
S2 Keep out of reach of children.
S46 If swallowed seek medical advice, , seek medical advice immediately and show this container or label.
CAS Number: 188425-85-6

32. References:

MBOSCPYRA_62974-0308.pdf

Acknowledgments:

Collated by HerbiGuide. Phone 08 98444064 or www.HerbiGuide.com.au for more information.