CHLORPYRIFOS EC

1_Trade_NameManufacturerForm
4FARMERS CHLORPYRIFOS 500 INSECTICIDE4 FARMERS AUSTRALIA PTY LTDEMULSIFIABLE CONCENTRATE
AC CHOP 500 INSECTICIDE AND TERMITICIDEAXICHEM PTY LTDEMULSIFIABLE CONCENTRATE
ACCENSI CHLORPYRIFOS 500 INSECTICIDEACCENSI PTY LTDEMULSIFIABLE CONCENTRATE
ACP CHLORPYRIFOS 500 INSECTICIDEAUSTRALIS CROP PROTECTION PTY LTDEMULSIFIABLE CONCENTRATE
AGROCN CHLORPYRIFOS 500 EC INSECTICIDE AND TERMITICIDESHANGHAI AGROCHINA CHEMICAL CO. LTD.EMULSIFIABLE CONCENTRATE
AGRO-ESSENCE CHLORPYRIFOS 500 INSECTICIDEAGRO-ALLIANCE (AUSTRALIA) PTY LTDEMULSIFIABLE CONCENTRATE
AGVANTAGE CHLORPYRIFOS 500 EC INSECTICIDELANDMARK OPERATIONS LIMITEDEMULSIFIABLE CONCENTRATE
APPARENT DINGO 500 INSECTICIDEAPPARENT PTY. LTD.EMULSIFIABLE CONCENTRATE
AW CUFT 500 INSECTICIDE AND TERMITICIDEAGRI WEST PTY LIMITEDEMULSIFIABLE CONCENTRATE
BIOCHLOR 500 GRAIN PROTECTANTGROW CHOICE PTY LIMITEDEMULSIFIABLE CONCENTRATE
CHEMFORCE CHLORPYRIFOS 500 INSECTICIDECHEMFORCE 2010 PTY LTDOIL MISCIBLE LIQUID
CHEMICIDE 500 INSECTICIDEHEXTAR CHEMICALS PTY LTDEMULSIFIABLE CONCENTRATE
CHLORBAN 500 EC INSECTICIDEUPL AUSTRALIA LIMITEDEMULSIFIABLE CONCENTRATE
CONQUEST CHLORPYRIFOS 500 INSECTICIDECONQUEST CROP PROTECTION PTY LTDEMULSIFIABLE CONCENTRATE
COUNTRY CHLORPYRIFOS 500 INSECTICIDEACCENSI PTY LTDEMULSIFIABLE CONCENTRATE
CUTTER CHLORPYRIFOS 500 EC INSECTICIDEIVORYCHEM AUSTRALIA PTY LTDEMULSIFIABLE CONCENTRATE
CYREN 500 EC INSECTICIDEFMC AUSTRALASIA PTY LTDEMULSIFIABLE CONCENTRATE
CYREN 500 WP INSECTICIDECHEMINOVA AUSTRALIA PTY LIMITEDWETTABLE POWDER
CYREN PC INSECTICIDEFMC AUSTRALASIA PTY LTDEMULSIFIABLE CONCENTRATE
DAVID GRAYS CHLORPYRIFOS 500DAVID GRAY & CO. PTY LIMITEDEMULSIFIABLE CONCENTRATE
DAVID GRAYS PCO CHLORPYRIFOS 500DAVID GRAY & CO. PTY LIMITEDEMULSIFIABLE CONCENTRATE
DIPLOMAT GRAIN PROTECTANTIMTRADE AUSTRALIA PTY LTDEMULSIFIABLE CONCENTRATE
DIPLOMAT INSECTICIDEIMTRADE AUSTRALIA PTY LTDEMULSIFIABLE CONCENTRATE
eChem Chlorpyrifos 500 InsecticideECHEM (AUST) PTY LIMITEDEMULSIFIABLE CONCENTRATE
EZYCROP CHLORPYRIFOS 500 INSECTICIDEEZYCROP PTY LTDEMULSIFIABLE CONCENTRATE
FARMALINX CHLORPOS 500 EC INSECTICIDEFARMALINX PTY LTDEMULSIFIABLE CONCENTRATE
FARMOZ CYREN 500 WP INSECTICIDEADAMA AUSTRALIA PTY LIMITEDWETTABLE POWDER
FARMOZ STRIKE-OUT PC TERMITICIDE AND INSECTICIDEADAMA AUSTRALIA PTY LIMITEDEMULSIFIABLE CONCENTRATE
FORTUNE 500 (PUBLIC HEALTH) INSECTICIDEPCT HOLDINGS PTY LTDEMULSIFIABLE CONCENTRATE
FORTUNE 500 EC (AGRICULTURE) INSECTICIDEPCT HOLDINGS PTY LTDEMULSIFIABLE CONCENTRATE
FORTUNE 500 TERMI-EC (TERMITE) TERMITICIDEPCT HOLDINGS PTY LTDEMULSIFIABLE CONCENTRATE
GENERIFOS 500EC INSECTICIDEGROW CHOICE PTY LIMITEDEMULSIFIABLE CONCENTRATE
GENFARM CHLORPYRIFOS 500 INSECTICIDELANDMARK OPERATIONS LIMITEDEMULSIFIABLE CONCENTRATE
HALLEY CHLORPYRIFOS 500 INSECTICIDEHALLEY INTERNATIONAL ENTERPRISE (AUSTRALIA) PTY LTDEMULSIFIABLE CONCENTRATE
HUILONG CHLORPYRIFOS 500 EC INSECTICIDEHUILONG AGROCHEMICALS AUSTRALIA PTY LTDEMULSIFIABLE CONCENTRATE
IMTRADE CHLORPYRIFOS 500 INSECTICIDEIMTRADE AUSTRALIA PTY LTDEMULSIFIABLE CONCENTRATE
KENSO AGCARE KENSBAN 500 INSECTICIDEKENSO CORPORATION (M) SDN. BHD.EMULSIFIABLE CONCENTRATE
LORSBAN 500 EC INSECTICIDEDOW AGROSCIENCES AUSTRALIA LIMITEDEMULSIFIABLE CONCENTRATE
MACPHERSONS CHLORPYRIFOS 500 INSECTICIDETGAC AUSTRALIA PTY. LTD.EMULSIFIABLE CONCENTRATE
MACRO PROTECT CHLORPYRIFOS 500 INSECTICIDE AND TERMITICIDEMACROFERTIL AUSTRALIA PTY LTDEMULSIFIABLE CONCENTRATE
MISSION CHLORPYRIFOS 500 EC INSECTICIDEMISSION BELL HOLDINGS PTY LTDEMULSIFIABLE CONCENTRATE
NOVAGUARD CHLORPYRIFOS 500 INSECTICIDENOVAGUARD PTY LTDEMULSIFIABLE CONCENTRATE
NUFARM CHLORPYRIFOS 500 EC INSECTICIDENUFARM AUSTRALIA LIMITEDEMULSIFIABLE CONCENTRATE
NUFARM CHLORPYRIFOS PCO INSECTICIDENUFARM AUSTRALIA LIMITEDEMULSIFIABLE CONCENTRATE
OZCROP CHLORPYRIFOS 500 EC INSECTICIDEOZCROP PTY. LTD.EMULSIFIABLE CONCENTRATE
Oztec Chlorpyrifos 500EC InsecticideOZTEC RURAL PTY LTDEMULSIFIABLE CONCENTRATE
PIDGEON'S PEST CONTROLLER 500 TERMITICIDE AND INSECTICIDESUPERWAY GARDEN AG & PEST PRODUCTS PTY LTDEMULSIFIABLE CONCENTRATE
RAINBOW CHLORPYRIFOS 500 INSECTICIDESHANDONG RAINBOW INTERNATIONAL CO., LTD.EMULSIFIABLE CONCENTRATE
RELDAN GRAIN PROTECTORDOW AGROSCIENCES AUSTRALIA LIMITEDEMULSIFIABLE CONCENTRATE
Relyon Chlorphos 500EC InsecticideRURALCO HOLDINGS LIMITEDEMULSIFIABLE CONCENTRATE
SABAKEM CHLORPYRIFOS 500EC INSECTICIDESABAKEM PTY LTDEMULSIFIABLE CONCENTRATE
SABERO CHLORPYRIFOS 500EC INSECTICIDESABERO AUSTRALIA PTY LIMITEDEMULSIFIABLE CONCENTRATE
Sharda Chlorpyrifos 500 InsecticideSHARDA CROPCHEM ESPANA S.LEMULSIFIABLE CONCENTRATE
Sinon Chlorpyrifos 500 EC InsecticideSINON AUSTRALIA PTY LIMITEDEMULSIFIABLE CONCENTRATE
SMART CHLORPYRIFOS 500 INSECTICIDECROP SMART PTY LTDSUSPENSION CONCENTRATE
SPALDING CHLORPYRIFOS 500 INSECTICIDESPALDING HOLDINGS PTY. LTD.EMULSIFIABLE CONCENTRATE
STRIKE-OUT 500 EC INSECTICIDEADAMA AUSTRALIA PTY LIMITEDEMULSIFIABLE CONCENTRATE
STRIKE-OUT 500 WP INSECTICIDEADAMA AUSTRALIA PTY LIMITEDWETTABLE POWDER
SUREFIRE FORTUNE 500 MULTI-PURPOSE INSECTICIDE AND TERMITICIDEPCT HOLDINGS PTY LTDEMULSIFIABLE CONCENTRATE
TITAN CHLORPYRIFOS 500 TERMITICIDE AND INSECTICIDETITAN AG PTY LTDEMULSIFIABLE CONCENTRATE
WELLFARM CHLORPYRIFOS 500 EC INSECTICIDEWELLFARM PTY LTDEMULSIFIABLE CONCENTRATE
WSD CHLORPYRIFOS 500 EC INSECTICIDEWSD AGRIBUSINESS PTY LTDEMULSIFIABLE CONCENTRATE

4. ACTIVE INGREDIENTS: CHLORPYRIFOS 500g/L EC

5. COST: $7.42 per L or kg.

6. CHEMICAL GROUP: 1B.

7. RELATED PESTICIDES:

ACEPHATE 970g/kg
AZINPHOS-METHYL 200 g/L
CHLORPYRIFOS 500g/L EC
DIAZINON 800g/L or kg
DIMETHOATE 400g/L
DIMETHOATE SD 400g/L
FENITROTHION 1000g/L
FENTHION 550g/L
MALDISON 500-1180g/L
METHAMIDOPHOS 580g/L
METHIDATHION 400g/L
OMETHOATE 290g/L
OMETHOATE 800g/L
PARATHION 450-500g/L
PHOSMET 150g/L
PROTHIOFOS 500g/L
Terbufos 150 g/kg
TRICHLORFON 500g/L

8. GENERAL DESCRIPTION:

A non systemic, contact insecticide for some sucking and chewing insects.
At 300 mL/ha it will provide around 12 days protection against Red legged Earth Mite.

9. APPLICATION METHODS AND TIPS:

The addition of 500 g of salt per 100 L of spray solution may improve the control of sucking insects.
Dangerous to bees - do not spray plants where bees are foraging.
Best results when temperature is less than 25 C and relative humidity is more than 65%.
Maximum tank storage time - 1 week.
Avoid situations where pesticide may run off treated areas.

10. ADJUVANTS, WETTERS, OILS:

Compatible with Uptake, Hasten and BS 1000.
Not recommended with Synnertrol.

11. EQUIPMENT:

Aerial - Micronair rotary atomizers producing 150-250 micron droplets.
Boom - Hydraulic nozzles producing 150-250 micron droplets.

12. SPRAYER WASH OUT AND DECONTAMINATION:

Triple rinse with water plus wetting agent.

13. WATER OR CARRIER DATA:

Boom spray - 20 Lwater /ha minimum.
Aerial 10-50 L water/ha.
In furrow - 20 L water/ha.

14. WEATHER:

Don't spray when temperature is more than 28C or relative humidity is less than 40%.

15. RAINFASTNESS:

4 hours

16. SOIL:

17. PLANT HEALTH and OTHER EFFECTS:

May damage poinsettias, camellias, roses, azaleas and ivy.
May cause reddening of foliage especially on stressed plants or cotton.

18. WITHHOLDING PERIODS:

Asparagus: Harvest - 14 days.
Avocado: Harvest - 7 days.
Bananas: Harvest - 14 days.
Celery: Harvest - 14 days.
Cereals: Harvest - 10 days.
Cereals : Cutting and grazing - 2 days.
Citrus: Harvest - 14 days.
Cole crops: Harvest - 5 days.
Cotton : Cutting and grazing - 4 weeks.
Cotton : Harvest - 4 weeks.
Cucurbits: Harvest - 5 days.
Forage crops : Cutting and grazing - 2 days.
Grapevines: Harvest - 14 days.
Kiwifruit: Harvest - 14 days.
Legume Pasture : Cutting and grazing - 2 days.
Legumes : Cutting and grazing - 2 days.
Mango : Harvest - 21 days.
Pasture, animal feeds, grasses, grass-like plants : Cutting and grazing - 2 days.
Pome fruit: Harvest - 14 days.
Sorghum (grain): Harvest - 2 days.
Stone fruit: Harvest - 14 days.
Sugarcane: Harvest - 7 days.
Tomatoes: Harvest - 3 days.
Turf: : Cutting and grazing - 2 days. Do not feed turf/lawn clippings from treated area to poultry or livestock.
Asparagus: Harvest - 14 days.
Avocado: Harvest - 7 days.
Bananas: Harvest - 14 days.
Celery: Harvest - 14 days.
Cereals: Harvest - 10 days.
Cereals : Cutting and grazing - 2 days.
Citrus: Harvest - 14 days.
Cole crops: Harvest - 5 days.
Cotton : Cutting and grazing - 4 weeks.
Cotton : Harvest - 4 weeks.
Cucurbits: Harvest - 5 days.
Forage crops : Cutting and grazing - 2 days.
Grapevines: Harvest - 14 days.
Kiwifruit: Harvest - 14 days.
Legume Pasture : Cutting and grazing - 2 days.
Legumes : Cutting and grazing - 2 days.
Mango : Harvest - 21 days.
Pasture, animal feeds, grasses, grass-like plants : Cutting and grazing - 2 days.
Pome fruit: Harvest - 14 days.
Sorghum (grain): Harvest - 2 days.
Stone fruit: Harvest - 14 days.
Sugarcane: Harvest - 7 days.
Tomatoes: Harvest - 3 days.
Turf: : Cutting and grazing - 2 days. Do not feed turf/lawn clippings from treated area to poultry or livestock.

19. PLANT BACK PERIODS or RECROPPING INTERVALS:

20. MODE OF ACTION:

Active by contact, ingestion or vapour for insects. Acts on the insects nervous system.
A group 1B,organophosphorous, non systemic insecticide.
Acetylcholinesterase inhibitor.

21. PESTICIDE RESISTANCE:

Maximum of 3 sprays per season for Helicoverpa.

22. TOXICITY:

Poison schedule - S6


Summary:
Details:
Poison schedule - S
Mammalian toxicity - Moderate toxicity.
Acute oral LD50 - 135-163 mg/kg
Acute dermal LD50 - 1500 mg/kg
Skin - Not irritating.
Eye - Mildly irritating
Main exposure routes - Handling concentrate. Air blast application.
Vapour inhalation - LC50 - > mg/L air (rat).
Chronic oral toxicity NOEL - ppm for two years.
Not mutagenic or teratogenic (i.e. does not cause cancer or reproductive problems).
Acceptable Daily Intake (ADI) -

23. TOXICITY SYMPTOMS:

Initial symptoms include headache, nausea, lack of appetite and fatigue during exposure or several hours later. Dizziness, vomiting, stomach pains, contracted pupils, muscle weakness, twitching, tremor, slow heart beat, blurred vision and sweating may occur with higher exposure levels.
Continual low level exposure may cause influenza like symptoms.

24. FIRST AID:

Contact a doctor or poison information centre on 008 119 244.
Give atropine (0.6mg) tablets every quarter hour then every half hour until signs of flushed face, dilated pupils, dry mouth and fast pulse appear. Medical attention must be sought after taking atropine.
Remove contaminated clothing and wash skin.
If breathing has stopped apply resuscitation
Poisoning usually occurs through skin absorption. Effects are cumulative and dangerous levels may develop before symptoms become noticeable. If you are exposed to organophosphate for more than 30 hours per month then levels of acetylcholinesterase enzyme should be regularly checked. If levels drop below 60% of normal then work with organophosphates should stop until levels improve. This may take several weeks.

25. PROTECTIVE CLOTHING:

26 RE ENTRY PERIODS and OTHER SAFETY ISSUES:

After spray has dried.

27. PROPERTIES:

Product appearance - Amber to light brown liquid. Characteristic aromatic odour.
Shelf Life - 2 years.
Product Flammability - Flammable. Flashpoint - 66 °C
Half life in water - 0.2-4 days.
Water solubility at 25 C. - 1.4 mg/L. Low. Completely emulsifies in water.
Oil solubility -
Octanol:Water ratio at 25 C. - at pH 5.
Sorption to soil Koc - 6070 mL/g. Strong.
Vapour Pressure - Chlorpyrifos: 1.87 x 10(-5) mm Hg at 25°C. Solvent: 0.6 mm Hg at 20°C
Dissociation constant - pKa.
Melting point - C.
Boiling point - Decomposes.
Molecular weight -
Density - SG = 1.084
Formula - C9H9Cl3NO3PS
pH - 5.9 (1% aqueous solution)

28. ENVIRONMENTAL FATE:

Rapidly absorbed and metabolised then excreted in urine mainly.
Very resistant to leaching.
Degraded by microbes at variable rates with half lives up to 279 days in some soils.
Decomposes rapidly at temperatures above 160°C.
Strongly adsorbed and not mobile in soil.

Summary - Dangerous to bees.
Birds - Extremely toxic. LD50 is 3-76 mg/kg.
Fish - Extremely toxic. LC50 is 2.4-3 ppm.
Invertebrates - Extremely toxic. LC50 is 0.18ppb to 1.5ppm
Bees - Highly toxic. Topical - 0.07ìg/bee. Oral - 0.36ìg/bee
It has a half life in soil of 1-120 days.
Half life in water - 0.2-4 days.
It has an EPA classification for soil mobility that ranges from
Ground water contamination - unlikely. Low likelihood of leaching. Low likelihood of runoff.
Accumulation in milk and tissues.
pH stability - Unstable at ph>5
Photolysis rate - 21-28 days.
Hydrolysis half life - 0.01 days at pH12. 141.6 days at pH6.1
Biodegradation rate - Slow to readily and rapidly biodegradable in the environment.
Negligable bio-accumulation potential.

29. COMPATIBILITY:

See HerbiGuide for compatibility with other herbicides, insecticides and fungicides.
See HerbiGuuide for a full list of pesticide compatibilities.
Compatible with diammonium phosphate, ethion, fluometuron, spray oils, tetradifon, limestone, mepiquat chloride, miloreanite, mono ammonium sulfate, potash, sulphur coated urea, triple superphosphate, urea.
Not compatible with alkaline solutions, Bordeaux mixture, fixed coppers, liquid and organic coppers, Lime sulphur, wettable sulphur, iron sulphate, manganese sulphate, zinc oxysuphate.

30. REGISTERED CROPS, INSECTS and DISEASES.

See HerbiGuide Species Solutions Tab for registered uses.

31. GOVERNMENT AND REGULATORY INFORMATION:

Dangerous Goods Class - 6.1
Hazchem Code - 2X
Packaging Group - 3.
EPG - 6B3.
UN Number - 3018
Worksafe Classification - Hazardous.

32. References:

Wendy C Quayle CSIRO

Acknowledgments:

Collated by HerbiGuide. Phone 08 98444064 or www.HerbiGuide.com.au for more information.