Florasulam plus fluroxypyr

1 Trade nameManufacturerForm
OUTSHINE HERBICIDEADAMA AUSTRALIA PTY LIMITEDSUSPOEMULSION
Also sold as Crest

2 PRICE:

$25/L

3 ACTIVE INGREDIENTS: Florasulam2.5g+fluroxypyr100g/L

4 CHEMICAL GROUP: B,I

5 RELATED HERBICIDES:

2,4-D amine 5002,4-D Amine 500g/L
2,4-D amine 6252,4-D Amine 625g/L
2,4-D amine plus Dicamba2,4-D 333g/L + dicamba 166g/L
2,4-D ester 8002,4-D Ester 800g/L
2,4-D ester plus Garlon2,4-D ester 530g/L + triclopyr 200g/L
2,4-D LV ester2,4-D LV ester 680g/L (or600)
2,4-DB 5002,4-DB 500g/L
2,4-DB plus MCPA2,4-DB 200g/L + MCPA 250g/L
AccessPicloram 120g/L + triclopyr 240g/L
Aminopyralid plus picloram gelAminopyralid 4.47g/L+picloram 44.7g/L
BensulfuronBensulfuron 600g/kg
BroadstrikeFlumetsulam 800g/kg
ChlorsulfuronChlorsulfuron 750g/kg
CrusaderPyroxsulam 215g/kg + cloquintocet-mexyl 451.5g/kg
CrusaderPyroxsulam 30g/L + cloquintocet-mexyl 90g/L
Dicamba 25 plus MCPA 150Dicamba 25g/L + MCPA 150g/L
Dicamba 500Dicamba 500g/L
Dicamba 700Dicamba 700g/kg (or 750 g/kg)
Dicamba plus MCPADicamba 80g/L + MCPA 340g/L
EclipseMetosulam 100g/L
ExpressTribenuron methyl 750g/kg
FallowBoss2,4-Dam 300g/L+Aminopyralid 7.5g/L+picloram 75g/L
FlameImazapic 240g/L (to 900g/kg)
Garlon 600Triclopyr 600g/L (or 755g/L)
Grazon ExtraAminopyralid 8g/L+picloram 100g/L+triclopyr 300g/L
Harmony MMetsulfuron 68g/kg + thifensulfuron-methyl 682g/kg
HotshotAminopyralid salt 10g/L + fluroxypyr-meptyl 140g/L
Imazapic plus ImazapyrImazapic 525 + Imazapyr 175g/L
ImazapyrImazapyr 250g/L or 750g/kg
IntervixImazamox 33g/L + imazapyr 15g/L
Iodosulfuron 100Iodosulfuron 100g/kg
Iodosulfuron plus mefenpyrIodosulfuron 100g/L + mefenpyr
LightningImazapyr 175g/L + imazethapyr 525g/L
Logran 750Triasulfuron 750g/kg
LontrelClopyralid 300g/L
Lontrel 750Clopyralid 750g/kg
MCPA amineMCPA 500-750g/L
MCPA LVEMCPA LV ester 500g/L
MCPB 400MCPB 400g/L
Mesosulfuron 30Mesosulfuron 30g/L
Metsulfuron-methylMetsulfuron 600g/kg
PicloramPicloram 240g/L
Picloram plus TriclopyrPicloram 100g/L + triclopyr 300g/L
QuincloracQuinclorac 750g/kg (or180or200)
Raptor WG 700Imazamox 700 g/kg
SempraHalosulfuron 750g/kg
SpinnakerImazethapyr 700g/kg (or 240g/L)
Starane 200Fluroxypyr 200-400g/L
SulfometuronSulfometuron 750g/kg
SulfosulfuronSulfosulfuron 750g/kg
TitusRimsulfuron 250g/kg
Tordon 242MCPA 420g/L + picloram 26g/L
Tordon 75-D2,4-D 300g/L + picloram 75g/L
Tordon DSPicloram amine 100g/L + triclopyr amine 200g/L
Tordon RegrowthMasterAminopyralid 25g/L+picloram100g/L+triclopyr 200g/L
TrifloxysulfuronTrifloxysulfuron 750g/kg
Tri-kombi24D Ester 800g/L + Dicamba 40g/L + Mecoprop 336g/L

6 GENERAL DESCRIPTION:

A post emergence, leaf absorbed, short residual herbicide applied as spray in water for control of some broad leaved weeds in turf grasses.

7 APPLICATION METHODS AND TIPS:

Best results in fine weather.

8 WEATHER:

Rainfast in 3 hours .
Frost effects:
Wind: DO NOT apply when wind speed is less than 3 or more than 20 kilometres per hour
Inversions: Do not apply during temperature inversions.
Temperature:
Delta T and relative humidity:

9 ADJUVANTS:

Wetting agents:
Spray oils:

10 WATER QUALITY:

Hard water:
Salty water:
Colloids:
pH:
Tank life:

11 COMPATIBILITY:

Trace elements.
See HerbiGuide Compatibilities button.

12 EQUIPMENT:

Boom sprays:

Carrier volume: 80-100 L/ha on label. >30 L/ha OK with finer nozzles. Up to 1000 L/ha OK for hand sprays.
Nozzles: Flat fan.
Pressure: 150-400 kPa.
Droplet size: Use coarse droplets to reduce the risk of drift.

Aerial application:

Carrier volume: 30 L/ha

13 SPRAYER DECONTAMINATION:

Clean Up:

Clean soon after spraying to reduce the risk of forming dried deposits that may be difficult to remove.
Remove filters and clean separately. Rinse with soapy water (e.g. 500 mL or g of Drive, Dynamo, Omo or Surf per 100 L water) or water plus 0.25% wetting agent and run through boom. Rinse with water.

Decontamination:

Remove filters and clean then soak in 500 mL household ammonia in 10 L water for 30 minutes.
Rinse sprayer with soapy water (e.g. 500 mL or g of Drive, Dynamo, Omo or Surf per 100 L water) or water plus 0.25% wetting agent and run through boom. Fill with 1 litre of 3% household ammonia per 100 litres of water and circulate for at least 15 minutes (allow to stand for several hours if possible). Triple rinse with water. Or use a commercial spray tank and equipment cleaner.
Rinse nozzles and filters in water and replace then rinse the whole system with water again.
Don't use chlorine based cleaners in combination with ammonia.

14 HERBICIDE RESISTANCE:

Tolerant plants are expected to occur and may dominate the weed population after repeated applications.

15 REPLANTING INTERVALS:

CropTime

16 WITHHOLDING PERIODS:

CropTypeTime
AllGrazingDo not feed clippings to livestock.
AllHarvestNot required.

17 RE-ENTRY PERIOD:

Wear protective clothing if in contact with the crop before the spray has dried.

18 PROTECTIVE CLOTHING:

Overalls, boots and washable hat. Use gloves and face shield when handling the concentrate.

19 SOIL:

Soil texture:
Soil pH:
Soil organic matter:
Soil moisture at application:

20 MODE OF ACTION:

It is a member of the pyridine and triazolopyrimidine sulfonanilide group of
herbicides. The product has the disrupters of cell growth and acetolactate
synthase (ALS) inhibitor modes-of-action. For herbicide resistance
management, it is a Group I + Group B herbicide.

Uptake and translocation:

Physiological effects:

Residual Life and Breakdown:

21 SELECTIVITY:

Crop tolerance:

Varietal sensitivities:

Effect on Clover Species: Kills clover
Effect on Medic Species: Kills medic
Effect on Lucerne: Kills young lucerne
Effect on Native Plants: Kills some young native plants

22 DISEASE AND INSECT EFFECTS:

23 PLANT SYMPTOMS:

SECONDARY EFFECTS:

24 TOXICITY:

Summary:

Irritating to eyes and respiratory system, respiratory tract irritant.

Details:

SUSMP classification (Poison schedule): S5
Mammalian toxicity: Low toxicity.
Acute oral LD50(Rat):> 5,000 mg/kg (F); 2,000 mg/kg (M), [For comparison table salt is 3000 mg/kg]
Acute dermal LD50: > 5 ,000 mg/kg (rabbit).
Skin: Brief contact may cause slight skin irritation with local redness. May cause drying and flaking of the skin. Potential for contact allergy in mice.
Does not cause sensitisation.
Eye: May cause moderate eye irritation which may be slow to heal. May cause slight corneal injury. Vapour may cause eye irritation experienced as mild discomfort and redness. Category 2/2A (Serious eye damage/eye irritation)
Vapour inhalation: LC50 > 10 mg/L air (rat) (4 hour) (based on the components.
Not carcinogenic, mutagenic or teratogenic in animal studies (i.e. does not cause cancer or reproductive problems in animal tests).
Chronic oral toxicity: NOEL mg/kg for two years.
Acceptable Daily Intake (ADI):

Other Species:

Data based on Fluroxypyr:

Fish: Rainbow trout LC50 (96-h): >100 mg/L (Fluroxypyr).

>0.9 mg/L (Fluroxypyr-meptyl).
Rainbow trout NOEC (21-d): 0.2 (Fluroxypyr-meptyl).

Invertebrates: Daphnia magna EC50 (48-h): >100mg/L (Fluroxypyr).

>0.9 mg/L (Fluroxypyr-meptyl).

Invertebrates: Daphnia magna NOEC (21-d): 0.1 mg/L (Fluroxypyr-meptyl).

Algae: EC50 (96-h) : >100mg/L (Fluroxypyr).>0.9 (Fluroxypyr-meptyl).

Data Based on Florasulam:

Fish: Rainbow trout LC50 (semi -static test, 96-h): > 100 mg/L

Invertebrates: Daphnia magna EC50 (immobilization, 48-h): > 100 mg/L

Algae: Green algae EbC50 (static test, biomass growth inhibition, 72-h): 0.0611 mg/L

Birds: Mallard duck LD50 (Oral), Rat (oral): > 2,250 mg/kg bodyweight.

Bees: LD50 (Oral), Rat (oral): > 70.25 ìg/bee ; LD 50 (contact): > 100 ìg/bee

Earthworms: (LC50): > 1,033 mg/kg
Duckweed EC50 (Growth inhibition, cell density reduction, 14-d): 0.0413 mg/L

Accumulation:

25 TOXICITY SYMPTOMS:

Symptoms may include headache, irritation of nose and throat and increased secretion of mucous in the nose and throat.
Symptoms may include stinging and reddening of eyes and watering which may become copious. If exposure is brief, symptoms should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent damage.

26 FIRST AID:

If SWALLOWED: Wash out mouth with water. Do NOT give anything by mouth to a semiconscious or unconscious patient. Do NOT induce vomiting.
If in EYES: Hold eyelids open and wash eyes with plenty of water for 5 minutes, remove contact lenses if present and wash for a further 10 minutes. See a doctor if symptoms persist.
If on SKIN: Remove contaminated clothing. Wash skin thoroughly with soap and water. If skin irritation or rash occurs: Get medical advice.

If INHALED: Remove patient to fresh air. See a doctor if symptoms persist.
Advice to doctor: Treat symptomatically.
Contact the Poisons Information Centre on 131126.

27 ENVIRONMENTAL FATE:

Half life in soil:
Half life in water: days at pH5 and 35 C.
It has an EPA classification for soil mobility that ranges from
It has a leaching index of . (for comparison, trifluralin is 0-1 and chlorsulfuron is 25-30).
Ground water contamination:
Accumulation in milk and tissues:
pH stability:
Photolysis rate:
Hydrolysis half life:
Biodegradation rate:
Bioconcentration factor (BCF):

28 REGISTERED CROPS:

See HerbiGuide Species Solution tab.

29 REGISTERED WEEDS:

See HerbiGuide Species Solution tab.

30 REGULATION AND LEGAL:

APVMA Numbers:
UN number: 3082
CAS numbers:
OPP Chemical Code:
Hazchem code: 3Z.
SWA classification: Hazardous according to the criteria of SWA.
Xi, Irritating. N, Dangerous to the environment.
Land transport: ADG
Dangerous goods class (ADG): Class 9: Miscellaneous Dangerous Goods.
Sea transport: IMDG
International Maritime Dangerous Goods Code (IMDG):
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Fluroxypyr, Florasulam).
Technical Name:
Hazard Class: Dangerous (Class 9 Environmentally Hazardous)
ID Number: .
Packaging group: III
EMS Number:
EPG:
Marine Pollutant:
Air transport: IATA/ICAO
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Fluroxypyr, Florasulam).
Technical Name:
ID Number:
Packaging group: III
Cargo Packing Instructions:
Passenger Packing Instructions:
Environmental Hazard:
Dangerous (Class 9 Environmentally Hazardous)

Risk phrases:
Flammable liquids Category 4
Skin Corrosion /Irritation Category 2
Serious eye damage/eye irritation Category 2/2A
Specific Target Organ Toxicity - Single Exposure Category 3
Florasulam

Hazardous to the aquatic environment (acute) - category 1

Hazardous to the aquatic environment (chronic) - category 1

Fluroxypyr

Hazardous to the aquatic environment (acute) - category 1

Hazardous to the aquatic environment (chronic) - category 1
Safety phrases:
Hazard Statements:
H227: Combustible liquid.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H336: May cause drowsiness or dizziness.
H410: Very toxic to aquatic life with long lasting effects.
Hazard Symbols:

Records: Are required within 24 hours and kept for 2 years.
Buffer zones:
Aquatic environments:
40-60 m for aerial application
10-15 m for ground application
Terrestrial environments:
250-750 m for aerial application
40-100 m for ground application

31 PROPERTIES:

See individual component florasulam and fluroxypyr for more information
Colour: Off-white liquid.

Odour: Characteristic odour.
Form: Liquid
Chemical name:
Empirical formula:
IUPAC:
CAS: Florasulam 145701-23-1

Fluroxypyr (as 1-methylhepty ester) 81406-37-3
Water solubility: mg/L at 25 C at pH
Oil solubility:
Octanol:Water ratio: LogPow = at 25 C at pH 5.
Soil organic carbon absorption coefficient (Koc):
Vapour Pressure: at 25 C.
Vapour density:
Dissociation constant: pKa
Melting point: C.
Boiling point: C.
Molecular weight:
Bulk density:
Specific gravity: 0.94-1.04
Viscosity: 509mm2/s at 40°C.
pH: 5-6 (1% solution)
Flammability: Category 4.
Flashpoint: 60.6°C. Flammable Category 4 (GHS), C1 combustible (AS 1940)
Autoignition: C.
Corrosivity:
Shelf Life: years.
(When Stored under Ideal Conditions)

32 SPILLS:

Absorb spill with earth, sand, clay or absorbent material such as vermiculite.
Ventilate area after cleanup.

33 FIRE:

Extinguish with water spray, foam, carbon dioxide or dry agent.
Toxic fumes may be released in fire. Wear breathing apparatus or avoid smoke.

34 COMMENTS:

35 REFERENCES:

Adama (2018) Crest label 84528/117196 and SDS.
Ashton, F.M. and Crafts, A.S. (1981) Mode of Action of Herbicides. (Wiley-Interscience publication).
Kearney, P.C. and Kaufman, D.D. (1976). Herbicides. Chemistry, degradation and mode of action. Vol 1 & 2.

Acknowledgments:

Collated by HerbiGuide. For more information see www.herbiguide.com.au or phone 08 98444064.