Fluopyram plus trifloxystrobin

1_Trade_NameManufacturerForm
LUNA SENSATION FUNGICIDEBAYER CROPSCIENCE PTY LTDSUSPENSION CONCENTRATE

4. ACTIVE INGREDIENTS: Fluopyram 250g/L + trifloxystrobin 250g/L

5. COST: $564.76 per L or kg.

6. CHEMICAL GROUP: 7,11.

7. RELATED PESTICIDES:

Boscalid 200g/L + kresoxim-methyl 100 g/L
Boscalid 252g/kg + Pyraclostrobin
Fluopyram 250g/L + trifloxystrobin 250g/L
Penflufen 154g/L + trifloxystrobin 154g/L

8. GENERAL DESCRIPTION:

An agricutural fungicide.

9. APPLICATION METHODS AND TIPS:

Apply less than 4 application per season and a maximum of 2 L/ha.
Ensure thorough coverage.
Application with foliar fertilisers may result in leaf tipping.
Use mixed spray immediately.
It may have an adverse effect on predatory bugs (Orius spp.) if used where IPM is practised. Safety to ladybirds, syrphid flies and lacewings has not been evaluated.
DO NOT apply with spray droplets smaller than a MEDIUM spray droplet size category according to nozzle manufacturer specifications that refer to the ASABE S572 Standard or the BCPC Guideline.
DO NOT apply in orchards when the wind speed is less than 3 or more than 20 kilometres per hour as measured 15 metres outside of the orchard on the upwind side.
DO NOT direct the spray above trees during airblast applications. TURN OFF outward pointing nozzles at row ends and outer rows during airblast applications.
DO NOT apply during surface temperature inversion conditions at the application site.
Users of this product MUST make an accurate written record of the details of each spray application within 24 hours following application and KEEP this record for a minimum of 2 years. The spray application details that must be recorded are: 1.date with start and finish times of application; 2.location address and paddock/s sprayed; 3.full name of this product; 4.amount of product used per hectare and number of hectares applied to; 5.crop/situation and weed/pest; 6.wind speed and direction during application; 7.air temperature and relative humidity during application; 8.nozzle brand, type, spray angle, nozzle capacity and spray system pressure measured during application; 9.name and address of person applying this product. (Additional record details may be required by the State or Territory where this product is used.)
MANDATORY NO-SPRAY ZONES
DO NOT apply if there are aquatic or wetland areas including aquacultural ponds within 20 metres downwind from the application area.

10. ADJUVANTS, WETTERS, OILS:

None recommended.

11. EQUIPMENT:

12. SPRAYER WASH OUT AND DECONTAMINATION:

Triple rinse with water.

13. WATER OR CARRIER DATA:

14. WEATHER:

15. RAINFASTNESS:

16. SOIL:

17. PLANT HEALTH and OTHER EFFECTS:

May cause leaf tipping.

18. WITHHOLDING PERIODS:

Check MRL's if exporting.
Almonds: DO NOT HARVEST FOR 14 DAYS AFTER APPLICATION
Apples and pears: DO NOT HARVEST FOR 4 WEEKS AFTER APPLICATION
Grazing: DO NOT GRAZE LIVESTOCK IN TREATED ORCHARDS
EXPORT SLAUGHTER INTERVAL (ESI) - 30 DAYS
Livestock that has been grazed on or fed treated crops should be placed on clean feed for 30 days prior to slaughter.
Check MRL's if exporting.
Almonds: DO NOT HARVEST FOR 14 DAYS AFTER APPLICATION
Apples and pears: DO NOT HARVEST FOR 4 WEEKS AFTER APPLICATION
Grazing: DO NOT GRAZE LIVESTOCK IN TREATED ORCHARDS
EXPORT SLAUGHTER INTERVAL (ESI) - 30 DAYS
Livestock that has been grazed on or fed treated crops should be placed on clean feed for 30 days prior to slaughter.

19. PLANT BACK PERIODS or RECROPPING INTERVALS:

20. MODE OF ACTION:

It is a combination of a succinate dehydrogenase inhibitor (SDHI) and a quinone outside inhibitor (QoI) fungicide.

21. PESTICIDE RESISTANCE:

Some species may be resistant or develop resistance with continued application. Rotate with products from alternative groups.

22. TOXICITY:

Poison schedule - S5
Summary: Repeated exposure may cause allergic disorders. Suspected of causing cancer.
Details:
Poison schedule - S5
Mammalian toxicity -
Acute oral LD50 - 2000 mg/kg (rats), [For comparison table salt is 3000 mg/kg]
Acute dermal LD50 - >2000 mg/kg (rabbit).
Skin - Non irritant. Trifloxystrobin is sensitising.
Eye - Nonn irritant.
Vapour inhalation - LC50 - > 1.7 mg/L air (rat).
Chronic oral toxicity NOEL - ppm for two years.
Not mutagenic or teratogenic (i.e. Does not cause reproductive problems).
Acceptable Daily Intake (ADI) -
Carcinogenicity - Fluopyram caused at high dose levels an increased incidence of tumours in rats in the liver and thyroid. The tumours seen with Fluopyram were caused through a non-genotoxic mechanism,
which is not relevant at low doses. The mechanism that triggers these tumours is not relevant to humans.
Trifloxystrobin was not carcinogenic in lifetime feeding studies in rats and mice.

23. TOXICITY SYMPTOMS:

24. FIRST AID:

If SWALLOWED - Rinse mouth. Do NOT induce vomiting. Call a doctor or poison control centre immediately on 13 11 26
If in EYES - Irrigate for 15 minutes with plenty of water.
If on SKIN - Rinse with plenty of water, remove contaminated clothing, wash with soap and water. Use polyethyleneglycol 400 if available then wash with a water.
If INHALED - Remove patient to fresh air.
If patient has symptoms or is concerned contact a doctor immediately.
Advice to doctor - Treat symptomatically. No specific symptoms known or expected. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable. There is no specific antidote.
Call Poisons Information Centre on 13 11 26

25. PROTECTIVE CLOTHING:

Safety goggles and face shield.
Elbow length PVC gl;oves.
Cotton overalls and washable hat.
Boots.

26 RE ENTRY PERIODS and OTHER SAFETY ISSUES:

After spray has dried.

27. PROPERTIES:

Product appearance - White to beige suspension with a characteristic odour.
Shelf Life -
Product Flammability - Flashpoint > 100 C. Ignition temperature >370 C.
Not explosive.
Half life in water - days at pH5 and 35 C.
Water solubility at 25 C. - Suspension.
Oil solubility -
Octanol:Water ratio at 25 C. - at pH 5.
Vapour Pressure at 25 C. -
Dissociation constant - pKa.
Melting point - C.
Boiling point -
Molecular weight -
Density - 1.17 g/cm3 at 20 C.
pH - 5-8
Log Pow - Fluopyram: log Pow: 3,3.
Trifloxystrobin: log Pow: 4,5 at 25 °C.
Surface tension 38 mN/m at 25 °C. Determined in the undiluted form.
Corrosivity - Not oxidising.

28. ENVIRONMENTAL FATE:

Summary - Toxic to aquatic life.
It may have an adverse effect on predatory bugs (Orius spp.) if used where IPM is practised. Safety to ladybirds, syrphid flies and lacewings has not been evaluated.
Birds - toxicity.
Fish - high toxicity LC50 > 0.091mg/L 96 hours.
Invertebrates - high toxicity. LC50 > 0.086mg/L 48 hours.
Bees - toxicity
Aquatic plants - IC50 (Pseudokirchneriella subcapitata) 0.292 mg/L for growth rate with exposure time of 72 hours.
It has a half life in soil of .
It has an EPA classification for soil mobility that ranges from
Mobility in soil Fluopyram: Moderately mobile in soils
Trifloxystrobin: Slightly mobile in soils
Ground water contamination
Accumulation in milk and tissues. Does not bioaccumulate.
Bioaccumulation Fluopyram: Bioconcentration factor (BCF) 18
Trifloxystrobin: Bioconcentration factor (BCF) 431
Biodegradability - Fluopyram: not rapidly biodegradable
Trifloxystrobin: not rapidly biodegradable
Koc Fluopyram: Koc: 279
Trifloxystrobin: Koc: 2377

29. COMPATIBILITY:

See HerbiGuide for compatibility with other herbicides, insecticides and fungicides.
See HerbiGuide for a full list of pesticide compatibilities.
Application with foliar fertilisers may result in leaf tipping.

30. REGISTERED CROPS, INSECTS and DISEASES.

See HerbiGuide Species Solutions Tab for registered uses.

31. GOVERNMENT AND REGULATORY INFORMATION:

APVMA Numbers:
UN number: 3082
CAS numbers: Fluopyram 658066-35-4
Trifloxystrobin 141517-21-7
1,2-Propanediol 57-55-6
Mixture of 5-chlor-2-methyl-3(2H)-isothiazolon and 2-
methyl-2H-isothiazol-3-on 55965-84-9
1,2-Benzisothiazol-3(2H)-one 2634-33-5
OPP Chemical Code:
Hazchem code: 3Z.
NOHSC classification:
Land transport: ADG
Dangerous goods class (ADG): 9
Sea transport: IMDG
International Maritime Dangerous Goods Code (IMDG):
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (TRIFLOXYSTROBIN SOLUTION)
Technical Name:
Hazard Class: 9
ID Number:
Packaging group: III
EMS Number: F-A, S-F
EPG:
Marine Pollutant: Yes
Air transport: IATA/ICAO
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (TRIFLOXYSTROBIN SOLUTION)
Technical Name:
ID Number:
Packaging group: III
Cargo Packing Instructions:
Passenger Packing Instructions:
Environmental Hazard: Yes.
No Spray Zones: 20m to downwind aquatic areas.
Records:
Hazard Statrements:
H317 May cause an allergic skin reaction.
H351 Suspected of causing cancer.
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing spray mist.
P280 Wear cotton overalls buttoned to the neck and wrist (or equivalent clothing) and elbowlength
chemical resistant gloves.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.
P501 Dispose of contents/container in accordance with relevant Local, State or Territory
Government Regulations.

32. References:

Acknowledgments:

Collated by HerbiGuide. Phone 08 98444064 or www.HerbiGuide.com.au for more information.