Fluquinconazole

1. Trade Name 2. Manufacturer3. Formulation
BASF JOCKEY SYSTEMIC SEED FUNGICIDEBASF AUSTRALIA LTDFS
CROP CARE JOCKEY SYSTEMIC SEED TREATMENTCROP CARE AUSTRALASIA PTY LTDFS
JOCKEY STAYER SEED TREATMENT FUNGICIDEBAYER CROPSCIENCE PTY LTDFS
JOCKEY SYSTEMIC SEED FUNGICIDEBAYER CROPSCIENCE PTY LTDFS
MAXIFLO SEED TREATMENTCHEMTURA AUSTRALIA PTY LTDFS
QUANTUM SEED TREATMENTCHEMTURA AUSTRALIA PTY LTDFS

4. ACTIVE INGREDIENTS: Fluquinconazole 167g/L

5. COST: $61.60 per L or kg.

6. CHEMICAL GROUP: C.

7. RELATED PESTICIDES:

Cyproconazole 100 g/L
Cyproconazole 80g/L + propiconazole 250g/L
Epoxiconazole 125g/L
Epoxiconazole 75g/L
Fenarimol 120g/L
Fluquinconazole 167g/L
Flusilazole 200g/kg
Flutriafol 250g/L
Hexaconazole 50 g/L
Imazalil 800g/L
Myclobutanil 200g/L
Propiconazole 250g/L
Tebuconazole 430g/L
Triadimefon 125g/L or 500g/kg
Triadimenol 250g/L
Triforine 190g/L


8. GENERAL DESCRIPTION:

A systemic fungicide applied as a seed dressing.

9. APPLICATION METHODS AND TIPS:

Apply neat or mixed with water using equipment that provides even distribution of product on the seed. Agitate if left standing for more than 5 hours.

10. ADJUVANTS, WETTERS, OILS:

None required.

11. EQUIPMENT:

Use equipment suitable for flowable products with an adjustable output.

12. SPRAYER WASH OUT AND DECONTAMINATION:

Rinse with water immediately after use.

13. WATER OR CARRIER DATA:

Nil or less than 1.5 L water per tonne of seed.

14. WEATHER:

15. RAINFASTNESS:

16. SOIL:

17. PLANT HEALTH and OTHER EFFECTS:

Use on sound seed. Sow seed in the same season as it is treated.

May shorten coleoptile length of Canola seedlings causing emergence problems in crusting soils or where seed is plant more than 20 mm deep.

If growing produce for export then check import tolerances with the manufacturer.

18. WITHHOLDING PERIODS:

Canola: Cutting and grazing - 8 weeks. Do not cut for stockfeed or graze plants grown from treated seed for 8 weeks after planting.

Wheat: Cutting and grazing - 12 weeks. Do not cut for stockfeed or graze plants grown from treated seed for 12 weeks after planting.

Canola: Cutting and grazing - 8 weeks. Do not cut for stockfeed or graze plants grown from treated seed for 8 weeks after planting.

Wheat: Cutting and grazing - 12 weeks. Do not cut for stockfeed or graze plants grown from treated seed for 12 weeks after planting.

19. PLANT BACK PERIODS or RECROPPING INTERVALS:

Nil.

20. MODE OF ACTION:

Quinazolinine based triazole fungicide. Low water solubility allows uptake over a long period which provides extended control. Water based flowable formulation.

Inhibits demethylase enzyme which is involved in sterol synthesis in susceptible fungi.

Contact, residual, disinfectant and preventative action.

21. PESTICIDE RESISTANCE:

Some strains of fungi may have or develop resistance.

22. TOXICITY:

Poison schedule - S6

Harmful if swallowed

May irritate eyes

Not irritating or sensitising to skin. Negligable skin penetration.

Mist may be harmful if inhaled.

Evidence of non genotoxic effects but not relevant to humans.

Oral LD50 rat - 429-492 mg/kg.

Dermal LD50 rat - >4000 mg/kg

NOEL - 0.9 mg/kg/day.

May produce toxic fumes if burnt.



Summary:

Details:

Poison schedule - S

Mammalian toxicity -

Acute oral LD50 - mg/kg (rats), [For comparison table salt is 3000 mg/kg]

Acute dermal LD50 - > mg/kg (rabbit).

Skin -

Eye -

Vapour inhalation - LC50 - > mg/L air (rat).

Chronic oral toxicity NOEL - ppm for two years.

Not mutagenic or teratogenic (i.e. does not cause cancer or reproductive problems).

Acceptable Daily Intake (ADI) -

23. TOXICITY SYMPTOMS:

Slight skin or eye irritation. Gastro intestinal irritation, possible liver damage, lethargy, weakness, ataxia, muscle tremors and incontinence.

Treat symptomatically. For large ingestions, use gastric lavage and charcoal. Monitor respiratory, cardiac and liver functions and central nervous system. Monitor liver enzymes. No specific antidote.

24. FIRST AID:

If Swallowed: Contact Poison Information Centre on 131126. Wash out mouth with water. Keep patient at rest.

If in Eyes: Flush eyes for 15 minutes with water. Ring a doctor.

If on Skin: Wash with soap and water. If irritation persists seek medical advice.

If Inhaled: Remove to fresh air. Seek medical advice.

25. PROTECTIVE CLOTHING:

Safety goggles. Full body clothing. Elbow length PVC gloves.

Use a dust mask if handling dry treated grain in confined spaces.

26 RE ENTRY PERIODS and OTHER SAFETY ISSUES:

27. PROPERTIES:

Flowable red liquid suspension with a faint odour.

Specific Gravity - 1.07 @ 20 degrees C.

Not combustible.

Solubility - Miscible.

pH - 7



Product appearance -

Shelf Life -

Product Flammability -

Half life in water - days at pH5 and 35 C.

Water solubility at 25 C. - ppm at pH

Oil solubility -

Octanol:Water ratio at 25 C. - at pH 5.

Vapour Pressure at 25 C. -

Dissociation constant - pKa.

Melting point - C.

Boiling point -

Molecular weight -

Density -

28. ENVIRONMENTAL FATE:

Don't feed treated seed to birds or livestock.

Immobile in soil.

Soil half life - 200-300 days at pH 7

Water half life - 21.9 days at pH 7

Sediment/water half life 12-15 days.

Photolysis half life 92.4 days (260-360 nm)

Fish 96 hour LC50 1.9 mg/L Trout & Carp

Crustaceans 48 hour EC50 > 5 mg/L Daphnia

Algae 72 hour EC50 > 0.014 mg/L.

Duck acute oral LD50 > 2000 mg/kg

Quail LC50 4392 mg/kg.

Honey Bees - low toxicity.

Earthworms - Low toxicity.



Summary -

Birds - toxicity.

Fish - toxicity LC50 > ppm.

Invertebrates - toxicity.

Bees - toxicity.

It has a half life in soil of .

It has an EPA classification for soil mobility that ranges from

Ground water contamination

Accumulation in milk and tissues.

29. COMPATIBILITY:

See HerbiGuide for compatability with other herbicides, insecticides and fungicides.

See HerbiGuide for a full list of pesticide compatabilies.

30. REGISTERED CROPS, INSECTS and DISEASES.

See Herbiguide Species Solutions Tab for registered uses.

31. GOVERNMENT AND REGULATORY INFORMATION:

Dangerous Goods Class - 6.1 - PESTICIDE, LIQUID, TOXIC, N.O.S. (contains fluquinconazole)

Hazchem Code -

Packaging Group - 3

EPG -

UN Number - 2902.

NOHSC Classification -

32. References:

Aventis (2002) Jockey label and MSDS 23/10/2000

Acknowledgments:

Collated by HerbiGuide. Phone 08 98444064 for more information.