Fluxapyroxad


4. ACTIVE INGREDIENTS: Fluxapyroxad 333g/L

5. COST: $218.94 per L or kg.

6. CHEMICAL GROUP: 7.

7. RELATED PESTICIDES:

Boscalid 500g/kg
Fluxapyroxad 333g/L
Penflufen 240g/L
Penthiopyrad 200g/L (or 500g/kg for Velista)

8. GENERAL DESCRIPTION:

A fungicide seed treatment for the suppression of rhizoctonia root rot and control of powdery mildew, scald, netblotch and bunt in cereals.

9. APPLICATION METHODS AND TIPS:

Mix with 400-600 mL water per 100 kg seed and ensure thorough coverage. Lower water rates can be used with special equipment.
Don't use on seed with more than 12% moisture or on sprouted or damaged seed.
Treated seed can be used in the following season.

10. ADJUVANTS, WETTERS, OILS:

None recommended

11. EQUIPMENT:

Clean with water.

12. SPRAYER WASH OUT AND DECONTAMINATION:

13. WATER OR CARRIER DATA:

400-600 mL water per 100 kg seed.

14. WEATHER:

15. RAINFASTNESS:

16. SOIL:

17. PLANT HEALTH and OTHER EFFECTS:

18. WITHHOLDING PERIODS:

Do not feed treated seed to stock.
Harvest: Not required.
Grazing: Do not graze plants from treated seed for 4 weeks after planting.
ESI is 2 days.
Do not feed treated seed to stock.
Harvest: Not required.
Grazing: Do not graze plants from treated seed for 4 weeks after planting.
ESI is 2 days.

19. PLANT BACK PERIODS or RECROPPING INTERVALS:

Not required.

20. MODE OF ACTION:

Carboxamide fungicide from the pyrazole group. Is is a succinate dehydrogenase inhibitor (SDI)
Broad spectrum fungicide. It inhibits the germination of spores, mycelial growth and sporulation of the fungus.
Controls many foliar diseases for an extended period.

21. PESTICIDE RESISTANCE:

Some species may be resistant or develop resistance with continued application. Rotate with products from alternative groups.

22. TOXICITY:

Poison schedule - S5
Summary:
Details:
Poison schedule - S5
Mammalian toxicity -
Acute oral LD50: Virtuall non toxic - >2000 mg/kg (rats), [For comparison table salt is 3000 mg/kg]
May be harmful if swallowed.
Acute dermal LD50: Virtuall non toxic. LD50 >5000 mg/kg (rat).
Skin - Not irritating. Non sensitising in mouse tests.
Eye - Not irritating. No eye irritation in rabit tests.
Vapour inhalation - May be harmful if inhaled. LC50 - >6.2 mg/L air (rat).
Chronic oral toxicity NOEL - ppm for two years.
Not mutagenic or teratogenic (i.e. does not reproductive problems).
Not carcinogenic (i.e. does not cause cancer in animal tests)
Acceptable Daily Intake (ADI) -

23. TOXICITY SYMPTOMS:

24. FIRST AID:

If SWALLOWED - Do Not induce vomitting. Rinse mouth out with water and give small sips to drink.
If in EYES - Irrigate for 15 minutes with plenty of water.
If on SKIN - Rinse with plenty of water, remove contaminated clothing, wash with soap and water.
If INHALED - Remove patient to fresh air.
If patient has symptoms or is concerned contact a doctor immediately.
Advice to doctor - Treat symptomatically. In case of ingestion gastric lavage should be considered in cases of significant ingestions
only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable.
There is no specific antidote.
Call Poisons Information Centre on 13 11 26

25. PROTECTIVE CLOTHING:

Safety goggles and face shield.
Elbow length PVC gl;oves.
Cotton overalls and washable hat.
Boots.

26 RE ENTRY PERIODS and OTHER SAFETY ISSUES:

Wear protective clothing and gloves if handling the seed before it as dried.

27. PROPERTIES:

Product appearance: Red suspension with a faintly aromatic odour.
Shelf Life:
Product Flammability: Not highly flammable. Ignition temperature 449C.
Half life in water: days at pH5 and 35 C.
Water solubility at 25 C. Dispersible. ppm at pH
Oil solubility:
Octanol:Water ratio at 25 C: Log Pow 3.5 at pH.
Vapour Pressure at 20 C: 23 hPa
Dissociation constant: pKa.
Melting point: -5.1C.
Boiling point: ~100C solvent.
Molecular weight -
Density - 1.16 g/cm3 at 20C
pH - 6-8 at 100% and 20C
Viscosity, dynamic: 27 mPa.s (20°C)

28. ENVIRONMENTAL FATE:

Summary:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Birds - Low toxicity. LC50 > 456 mg/kg. LD50 >4000 mg/kg.
Fish - High toxicicity LC50 = 1.46 mh/L 96 hour.
Invertebrates -Low toxicity. EC50 >100mg/L
Earthworms - Low toxicity. LC50 >1000 mg/kg.
Bees - Low toxicity. LD50 mg/bee
Algae - Moderate tosicity. EC50 1.175 mg/L
It has a half life in soil of .
The dissipation time Is longDT50 is in aerobic soil. In anaerobic soil the DT50 is .
It has an EPA classification for soil mobility that ranges from
Ground water contamination
Accumulation in milk and tissues.
FIRE
Keep out of smoke.

29. COMPATIBILITY:

See HerbiGuide for compatibility with other herbicides, insecticides and fungicides.
See HerbiGuide for a full list of pesticide compatibilities.
Compatible with Jockey, Stayer, Baytan T, Raxil T, Gaucho

30. REGISTERED CROPS, INSECTS and DISEASES.

See HerbiGuide Species Solutions Tab for registered uses.

31. GOVERNMENT AND REGULATORY INFORMATION:

Transport Information:
Domestic transport (ADG):
Hazard Class: 9
ID Number: UN3082
Packing Group: III
Hazard Label: 9, EHSM
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUNBSTANCE, LIQUID, N.O.S. (CONTAINS FLUXAPYROXAD)
Hazchem Code: 3Z

Sea transport (IMDG):
Hazard Class: 9
ID Number: UN3082
Packing Group: III
Hazard Label: 9, EHSM
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUNBSTANCE, LIQUID, N.O.S. (CONTAINS FLUXAPYROXAD)
Marine Pollutant: YES

Air transport (ICAO/IATA):
Hazard Class: 9
ID Number: UN3082
Packing Group: III
Hazard Label: 9, EHSM
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUNBSTANCE, LIQUID, N.O.S. (CONTAINS FLUXAPYROXAD)
Further information
Environmentally Hazardous Substances meeting the description of UN 3077 or UN 3082 are not subject to the Australian Dangerous Goods Code when transported by road or rail in packages not exceeding 500 kg
or 500 L.
Initial Emergency Response Guide IERG -
NOHSC Classification and phrases - Hazardous
N Dangerous for the environment
R-phrase(s)
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S-phrase(s)
S2 Keep out of reach of children.
S13 Keep away from food, drink and animal feeding stuffs.
S20/21 When using do not eat, drink or smoke.
S36/37 Wear suitable protective clothing and gloves.
S46 If swallowed, seek medical advice immediately and show this container or label.
S29/35 Do not empty into drains, this material and its container must be disposed of in a safe way.
S57 Use appropriate container to avoid environmental contamination.

CAS-No. Fluxapyroxad 907204-31-3
UN No. - 3082.

32. References:

Label MSDS 2016. FLUX333_70065-61412.pdf, FLUX333_70065-0415.pdf

Acknowledgments:

Collated by HerbiGuide. Phone 08 98444064 or www.HerbiGuide.com.au for more information.