Fluxapyroxad plus Pyraclostrobin

1_Trade_NameManufacturerForm
Lexicon Intrinsic Brand FungicideBASF AUSTRALIA LTD.SUSPENSION CONCENTRATE
SYSTIVA SEED TREATMENT FUNGICIDEBASF AUSTRALIA LTD.FLOWABLE CONCENTRATE FOR SEED TREATMENT

4. ACTIVE INGREDIENTS: Fluxapyroxad 167g/L+Pyraclostrobin 333g/L

5. COST: $770.00 per L or kg.

6. CHEMICAL GROUP: 7,11.

7. RELATED PESTICIDES:

Boscalid 200g/L + kresoxim-methyl 100 g/L
Boscalid 252g/kg + Pyraclostrobin
Fluopyram 250g/L + trifloxystrobin 250g/L
Fluxapyroxad 167g/L+Pyraclostrobin 333g/L
Penflufen 154g/L + trifloxystrobin 154g/L

8. GENERAL DESCRIPTION:

A broad spectrum fungicide for preventative and curative disease treatment for turf.

9. APPLICATION METHODS AND TIPS:

Best results in fine weather.
Ensure even coverage.
Do not apply where the slope exceeds 12%.
Do not apply if heavy rains or storms are forecast within 3 days.
Do not apply to water-logged soil.

10. ADJUVANTS, WETTERS, OILS:

None recommended

11. EQUIPMENT:

Clean with water.
Coarse droplets recommended on label to reducd the risk of drift.

12. SPRAYER WASH OUT AND DECONTAMINATION:

13. WATER OR CARRIER DATA:

400-2000 L/ha.
Use higher rates for soil borne diseases.

14. WEATHER:

Apply when the wind speed is 3-20 kilometres per hour.
Do not apply when there are hazardous surface temperature inversions.

15. RAINFASTNESS:

16. SOIL:

17. PLANT HEALTH and OTHER EFFECTS:

18. WITHHOLDING PERIODS:

Do not graze treated areas or feed clippings to stock.
Do not graze treated areas or feed clippings to stock.

19. PLANT BACK PERIODS or RECROPPING INTERVALS:

Not required.

20. MODE OF ACTION:

Protectant and curative.
Fluxapyroxad is a carboxamide fungicide from the pyrazole group 7 is a succinate dehydrogenase inhibitor (SDI) broad spectrum fungicide. It inhibits the germination of spores, mycelial growth and sporulation of the fungus.
Controls many foliar diseases for an extended period.

21. PESTICIDE RESISTANCE:

Some species may be resistant or develop resistance with continued application. Rotate with products from alternative groups.

22. TOXICITY:

Poison schedule - S5
Summary:
Details:
Poison schedule - S5
Mammalian toxicity -
Acute oral LD50: Virtuall non toxic - >2000 mg/kg (rats), [For comparison table salt is 3000 mg/kg]
May be harmful if swallowed.
Acute dermal LD50: Virtuall non toxic. LD50 >5000 mg/kg (rat).
Skin - Not irritating. Non sensitising in mouse tests.
Eye - Not irritating. Serious eye damage/irritation in rabit tests.
Vapour inhalation - May be harmful if inhaled. LC50 - >6.11 mg/L air (rat).
Chronic oral toxicity NOEL - ppm for two years.
Not mutagenic or teratogenic (i.e. does not reproductive problems).
Fluxapyroxad Assessment of carcinogenicity:
Indication of possible carcinogenic effect in animal tests. The effect is caused by an animal specific mechanism that has no human counter part.
Fluxapyroxad Assessment of reproduction toxicity:
The results of animal studies gave no indication of a fertility impairing effect. May cause harm to children via breast-feeding.
Assessment of teratogenicity: Indications of possible developmental toxicity/teratogenicity were seen in animal studies.
Acceptable Daily Intake (ADI) -

23. TOXICITY SYMPTOMS:

24. FIRST AID:

If SWALLOWED - Do Not induce vomitting. Rinse mouth out with water and give small sips to drink.
If in EYES - Irrigate for 15 minutes with plenty of water.
If on SKIN - Rinse with plenty of water, remove contaminated clothing, wash with soap and water.
If INHALED - Remove patient to fresh air.
If patient has symptoms or is concerned contact a doctor immediately.
Advice to doctor - Treat symptomatically. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable.
There is no specific antidote.
Call Poisons Information Centre on 13 11 26

25. PROTECTIVE CLOTHING:

Safety goggles and face shield.
Elbow length PVC gl;oves.
Cotton overalls and washable hat.
Boots.

26 RE ENTRY PERIODS and OTHER SAFETY ISSUES:

Wear protective clothing and gloves if handling the seed before it as dried.

27. PROPERTIES:

Product appearance: Off white liquid with a faint fruity odour.
Shelf Life:
Product Flammability: Not highly flammable.No flashpoint. Ignition temperature 535 C.
Half life in water: days at pH5 and 35 C.
Water solubility at 25 C. Dispersible. Ppm at pH
Oil solubility:
Octanol:Water ratio at 25 C: Log Pow 3.5 at pH.
Vapour Pressure at 20 C: 23 hPa
Dissociation constant: pKa.
Melting point: -5.1C.
Boiling point: ~100C solvent.
Molecular weight -
Density - 1.16 g/cm3 at 20C
pH - 6-8 at 100% and 20C
Viscosity, dynamic: 39 mPa.s (40°C, 100 1/s)

28. ENVIRONMENTAL FATE:

Summary: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Birds - Low toxicity. LC50 > 456 mg/kg. LD50 >4000 mg/kg.
Fish - High toxicicity LC50 = 0.0032 mg/L 96 hour.
Invertebrates -High toxicity. EC50 0.056mg/L
Earthworms - Low toxicity. LC50 >1000 mg/kg.
Bees - Low toxicity. LD50 mg/bee
Algae - Moderate toxicity. EC50 2.8 mg/L
It has a half life in soil of .
The dissipation time Is longDT50 is in aerobic soil. In anaerobic soil the DT50 is .
It has an EPA classification for soil mobility that ranges from
Ground water contamination: Not expected
Accumulation in milk and tissues.
Pyraclostrobin Bioconcentration factor: 379 - 507, Oncorhynchus mykiss
Accumulation in organisms is not to be expected.
Fluxapyroxad Bioaccumulation potential:
Bioconcentration factor: 36 - 37 (28 d), Lepomis macrochirus.
Does not accumulate in organisms.
Not readily biodegradable.
FIRE
Keep out of smoke.

29. COMPATIBILITY:

See HerbiGuide for compatibility with other herbicides, insecticides and fungicides.
See HerbiGuide for a full list of pesticide compatibilities.

30. REGISTERED CROPS, INSECTS and DISEASES.

See HerbiGuide Species Solutions Tab for registered uses.

31. GOVERNMENT AND REGULATORY INFORMATION:

APVMA Numbers: 8662
UN number: 3082
CAS numbers: Fluxapyroxad 907204-31-3
Pyraclostrobin 175013-18-0
Transport Information:
Domestic transport (ADG): Not a dangerous good.
Hazard Class: 9
ID Number: UN3082
Packing Group: III
Hazard Label: 9, EHSM
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUNBSTANCE, LIQUID, N.O.S. (CONTAINS FLUXAPYROXAD)
Hazchem Code: 3Z

Sea transport (IMDG):
Hazard Class: 9
ID Number: UN3082
Packing Group: III
Hazard Label: 9, EHSM
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUNBSTANCE, LIQUID, N.O.S. (CONTAINS FLUXAPYROXAD)
Marine Pollutant: YES

Air transport (ICAO/IATA):
Hazard Class: 9
ID Number: UN3082
Packing Group: III
Hazard Label: 9, EHSM
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUNBSTANCE, LIQUID, N.O.S. (CONTAINS FLUXAPYROXAD)

Further information:
Classification of the substance and mixture:
Acute toxicity: Cat. 4 (oral)
Acute toxicity: Cat. 5 (Inhalation - mist)
Carcinogenicity: Cat. 2
Specific target organ toxicity - single exposure: Cat. 3 (irritating to respiratory system)
Hazardous to the aquatic environment - acute: Cat. 1
Hazardous to the aquatic environment - chronic: Cat. 1
Hazard Statement:
H333 May be harmful if inhaled.
H302 Harmful if swallowed.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

Initial Emergency Response Guide IERG -
NOHSC Classification and phrases - Hazardous
N Dangerous for the environment
R-phrase(s)
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
CAS-No. Fluxapyroxad 907204-31-3
UN No. - 3082.

Buffer Zones: 100-375 metres for aquatic areas - see label.

32. References:

Label MSDS 2016. FLUX333_70065-61412.pdf, FLUX333_70065-0415.pdf
BASF Lexicon label FLUXPYRA_86662-116308.pdf
BASF Lexicon SDS FLUXPYRA_86662-0919

Acknowledgments:

Collated by HerbiGuide. Phone 08 98444064 or www.HerbiGuide.com.au for more information.