Garlon 600

1 Trade nameManufacturerForm
4FARMERS TRICLOPYR 600 HERBICIDE4 FARMERS AUSTRALIA PTY LTDEMULSIFIABLE CONCENTRATE
AC TRICKY 600 HERBICIDEAXICHEM PTY LTDEMULSIFIABLE CONCENTRATE
ACCENSI TRICLOPYR 600 HERBICIDEACCENSI PTY LTDEMULSIFIABLE CONCENTRATE
ACP TRICLOPYR 600 HERBICIDEAUSTRALIS CROP PROTECTION PTY LTDEMULSIFIABLE CONCENTRATE
AGRO-ESSENCE TRICLOPYR 600 HERBICIDEAGRO-ALLIANCE (AUSTRALIA) PTY LTDEMULSIFIABLE CONCENTRATE
AIMCO TRICLOPYR 600 HERBICIDEAIMCO KR AUSTRALIA PTY LTDEMULSIFIABLE CONCENTRATE
APPARENT AXEMAN 600 HERBICIDEAPPARENT PTY. LTD.EMULSIFIABLE CONCENTRATE
APPARENT TRICLOPYR 600 EC HERBICIDEAPPARENT PTY. LTD.EMULSIFIABLE CONCENTRATE
AUSAGRI TRICLOPYR 600 HERBICIDEAUSAGRI IP PTY LTDEMULSIFIABLE CONCENTRATE
AW TRICLOPYR 600 HERBICIDEAGRI WEST PTY LIMITEDEMULSIFIABLE CONCENTRATE
BIOSORB 600 HERBICIDEBIOTIS LIFE SCIENCE PTY LTDEMULSIFIABLE CONCENTRATE
CONQUEST MACA 600 HERBICIDECONQUEST CROP PROTECTION PTY LTDEMULSIFIABLE CONCENTRATE
CROP CARE GRANDO 600 HERBICIDECROP CARE AUSTRALASIA PTY LTDEMULSIFIABLE CONCENTRATE
ECHEM TRICLOPYR 600 HERBICIDEECHEM (AUST) PTY LIMITEDEMULSIFIABLE CONCENTRATE
EZYCROP TRICLOPYR 600 HERBICIDEEZYCROP PTY LTDEMULSIFIABLE CONCENTRATE
FARMALINX TRIPYR 600 EC HERBICIDEFARMALINX PTY LTDEMULSIFIABLE CONCENTRATE
FMC TRICLOPYR 600 HERBICIDEFMC AUSTRALASIA PTY LTDEMULSIFIABLE CONCENTRATE
GARLON 600 HERBICIDEDOW AGROSCIENCES AUSTRALIA LIMITEDLIQUID
GENEREX TRICLOPYR 600 HERBICIDEMACSPRED PTY. LTD.EMULSIFIABLE CONCENTRATE
GENFARM TRICLOPYR 600EC HERBICIDELANDMARK OPERATIONS LIMITEDEMULSIFIABLE CONCENTRATE
HALLEY TRICLOPYR 600 HERBICIDEHALLEY INTERNATIONAL ENTERPRISE (AUSTRALIA) PTY LTDEMULSIFIABLE CONCENTRATE
IMTRADE HURRICANE 600 HERBICIDEIMTRADE AUSTRALIA PTY LTDEMULSIFIABLE CONCENTRATE
IMTRADE HURRICANE ULTIMATE 750 HERBICIDEIMTRADE AUSTRALIA PTY LTDEMULSIFIABLE CONCENTRATE
IMTRADE TRICLOPYR 750 EC HERBICIDEIMTRADE AUSTRALIA PTY LTDEMULSIFIABLE CONCENTRATE
KENSO AGCARE TRICLOPYR 600 HERBICIDEKENSO CORPORATION (M) SDN. BHD.EMULSIFIABLE CONCENTRATE
MACRO PROTECT TRICLOPYR 600 HERBICIDEMACROFERTIL AUSTRALIA PTY LTDEMULSIFIABLE CONCENTRATE
NOVAGUARD TRICLOPYR 600 HERBICIDENOVAGUARD PTY LTDEMULSIFIABLE CONCENTRATE
NUFARM INVADER 600 HERBICIDENUFARM AUSTRALIA LIMITEDEMULSIFIABLE CONCENTRATE
OPAL TRICLOPYR 600 EC HERBICIDEOPAL AUSTRALASIA PTY LTDEMULSIFIABLE CONCENTRATE
OZCROP TRICLOPYR 600 EC HERBICIDEOZCROP PTY. LTD.EMULSIFIABLE CONCENTRATE
OZTEC TRICLOPYR 600 EC HERBICIDEOZTEC RURAL PTY LTDEMULSIFIABLE CONCENTRATE
PACIFIC TRICLOPYR 600 HERBICIDEPACIFIC AGRISCIENCE PTY LTDEMULSIFIABLE CONCENTRATE
PRO TRICLOPYR 600 HERBICIDEAUSTRALIAN PROGRESSIVE SUPPLIES PTY LTDEMULSIFIABLE CONCENTRATE
RAINBOW TRICLOPYR 600 EC HERBICIDESHANDONG RAINBOW INTERNATIONAL CO., LTD.EMULSIFIABLE CONCENTRATE
RANGER 600 HERBICIDEHEXTAR CHEMICALS PTY LTDEMULSIFIABLE CONCENTRATE
RC TRICLOPYR 600 HERBICIDERURALCHEM PTY LTDEMULSIFIABLE CONCENTRATE
REDEEM 600 HERBICIDESIPCAM PACIFIC AUSTRALIA PTY LTDEMULSIFIABLE CONCENTRATE
ROTAM BOGEN 600 EC HERBICIDEROTAM AGROCHEMICAL CO., LTD.EMULSIFIABLE CONCENTRATE
RYGEL TRICLOPYR 600 HERBICIDEPROFENG AUSTRALIA PTY LTDEMULSIFIABLE CONCENTRATE
SABAKEM TRICLOPYR 600EC HERBICIDESABAKEM PTY LTDEMULSIFIABLE CONCENTRATE
SABERO TRICLOPYR 600EC HERBICIDESABERO AUSTRALIA PTY LIMITEDEMULSIFIABLE CONCENTRATE
SAFARI 600EC HERBICIDEADAMA AUSTRALIA PTY LIMITEDEMULSIFIABLE CONCENTRATE
SAFARI 750 EC HERBICIDEADAMA AUSTRALIA PTY LIMITEDEMULSIFIABLE CONCENTRATE
SINDICATE 600 EC HERBICIDESINON AUSTRALIA PTY LIMITEDEMULSIFIABLE CONCENTRATE
SMART TRICLOPYR 600 HERBICIDECROP SMART PTY LTDEMULSIFIABLE CONCENTRATE
SPALDING TRICLOPYR 600 HERBICIDESPALDING HOLDINGS PTY. LTD.EMULSIFIABLE CONCENTRATE
SUPERWAY TRICLOPYR 600 HERBICIDESUPERWAY GARDEN AG & PEST PRODUCTS PTY LTDEMULSIFIABLE CONCENTRATE
TITAN TRICLOPYR 600 HERBICIDETITAN AG PTY LTDEMULSIFIABLE CONCENTRATE
TRICLOPS HERBICIDECROP CULTURE PTY LTDEMULSIFIABLE CONCENTRATE
TRIO TRICLOPYR 600 HERBICIDECTS CHEMICALS PTY LTDEMULSIFIABLE CONCENTRATE
UNILON 600 HERBICIDEUPL AUSTRALIA LIMITEDEMULSIFIABLE CONCENTRATE
WEEDPRO TRYCLOPS 600 HERBICIDEPCT HOLDINGS PTY LTDEMULSIFIABLE CONCENTRATE
WSD TRICLOPYR 600 HERBICIDEWSD AGRIBUSINESS PTY LTDEMULSIFIABLE CONCENTRATE
2 PRICE:$13.2/L


3 ACTIVE INGREDIENTS: 600 g/L triclopyr as the butoxyethyl ester

4 CHEMICAL GROUP: I. Pyridine

Pyridinyloxyacetic acids.

5 RELATED HERBICIDES:

2,4-D amine 5002,4-D Amine 500g/L
2,4-D amine 6252,4-D Amine 625g/L
2,4-D amine plus Dicamba2,4-D 250gL + dicamba 100g/L
2,4-D ester 8002,4-D Ester 800g/L
2,4-D ester plus Garlon2,4-D ester 530g/L + triclopyr 200g/L
2,4-D LV ester 6002,4-D LV ester 600-680g/L
2,4-DB 4002,4-DB 400g/L
2,4-DB 5002,4-DB 500g/L
2,4-DB plus MCPA2,4-DB 200g/L + MCPA 250g/L
AccessPicloram 120g/L + triclopyr 240g/L
Dicamba 200Dicamba 200
Dicamba 25 plus MCPA 150Dicamba 25g/L + MCPA 150g/L
Dicamba 500Dicamba 500g/L
Dicamba 700Dicamba 700g/kg (or 750 g/kg)
Dicamba plus MCPADicamba 80g/L + MCPA 340g/L
FallowBoss2,4-Dam 300g/L+Aminopyralid 7.5g/L+picloram 75g/L
Garlon 600Triclopyr 600g/L
Grazon ExtraAminopyralid 8g/L+picloram 100g/L+triclopyr 300g/L
HotshotAminopyralid salt 10g/L + fluroxypyr-meptyl 140g/L
LontrelClopyralid 300g/L
Lontrel 750Clopyralid 750g/kg
MCPA amineMCPA 500-750g/L
MCPA LVEMCPA LV ester 500g/L (or570)
MCPB 400MCPB 400g/L
PicloramPicloram 240g/L
Picloram plus TriclopyrPicloram 100g/L + triclopyr 300g/L
Starane 200Fluroxypyr 200-400g/L
Tordon 242MCPA 420g/L + picloram 26g/L
Tordon 75-D2,4-D 300g/L + picloram 75g/L
Tordon DSPicloram amine 100g/L + triclopyr amine 200g/L
Tordon RegrowthMasterAminopyralid 25g/L+picloram100g/L+triclopyr 200g/L
Tri-kombi24D Ester 800g/L + Dicamba 40g/L + Mecoprop 336g/L


6 GENERAL DESCRIPTION:

A translocated, leaf absorbed, selective herbicide used mainly for the control of woody broad-leaved weeds. Established grasses are not usually affected at normal use rates.

Registered in 1980 as a replacement for 2,4,5-T.

7 APPLICATION METHODS AND TIPS:

Apply to actively growing weeds.

Maximum tank storage time - 1 week.

8 WEATHER:

Rainfast in 1 hours.

Frost effects: Frost affected plants may be more tolerant to the herbicide application.

Wind:

Inversions: Avoid application during inversion conditions because drift may cause significant damage to broad leaved plants.

Temperature:

Delta T and relative humidity: Avoid application when Delta T is greater than

Soil moisture at application: Slightly more active due to root absorption when soil is moist.

9 ADJUVANTS:

Spray oils and Pulse® Penetrant are often useful for hard to kill species.

Non ionic wetting agents should be used in for most other applications.

The concentration of Pulse® Penetrant should be in the range of 0.1-0.25% of spray solution (Field et al 1995).

Uptake, D-C-Trate, D-C-Tron, Winter Spraying Oil, Summer Spraying Oil and BS 1000 are compatible.

Synertrol is not recommended.

10 WATER QUALITY:

Hard water

Colloids

pH

11 COMPATIBILITY:

12 EQUIPMENT:

Boom sprays:

Carrier volume:

Nozzles: Flat fan.

Pressure: 150-400 kPa.

13 SPRAYER DECONTAMINATION:

Clean Up:

Clean soon after spraying to reduce the risk of forming dried deposits that may be difficult to remove.

Remove filters and clean separately. Rinse with soapy water (eg 500 mL or g of Drive, Dynamo, Omo or Surf per 100 L water) or water plus 0.25% wetting agent and run through boom. Rinse with water.

Decontamination:

Remove filters and clean then soak in 500 mL household ammonia in 10 L water for 30 minutes.

Rinse sprayer with soapy water (eg 500 mL or g of Drive, Dynamo, Omo or Surf per 100 L water) or water plus 0.25% wetting agent and run through boom. Fill with 1% solution of ammonia and leave for several hours. Triple rinse with water. Or use a commercial spray tank and equipment cleaner.

Rinse nozzles and filters in water and replace.

Don't use chlorine based cleaners.

14 HERBICIDE RESISTANCE:

15 REPLANTING INTERVALS:

For rates up to 160 mL/ha
Crop Time
Barley 1 week
Chickpea1 week
Cotton2 weeks
Maize1 week
Sorghum1 week
Soybean1 week
Sunflower1 week
Wheat1 week

16 WITHHOLDING PERIODS:

CropTypeTime
AllHarvest 
AllGrazing 

17 RE-ENTRY PERIOD:

18 PROTECTIVE CLOTHING:

19 SOIL:

Soil texture: Little effect.

Soil pH: Little effect.

Soil organic matter: Little effect.

20 MODE OF ACTION:

Uptake and translocation:

Absorbed by leaves and roots and is readily translocated throughout the plant. The butoxyethyl ester formulations are absorbed in most soils which limits root uptake.

Physiological effects:

Disrupts the growth of plant cells by mimicking auxin, a plant hormone.

Residual Life and Breakdown:

Breaks down quickly in soils and water.

Selectivity:

Most broadleaf species affected and most grasses unaffected.

21 SELECTIVITY:

Crop tolerance:

Varietal sensitivities:

Effect on Clover Species:

Damages Clovers.

Effect on Medic Species:

Damages Medics

Effect on Lucerne:

Damages Lucerne.

Effect on Native Plants:

May damage native broadleaved plants especially at high rates. Little or no effect on native grasses, sedges and rushes.

22 DISEASE AND INSECT EFFECTS:

23 PLANT SYMPTOMS:

Produces typical auxin or hormone type symptoms including twisting, cupping and narrowing of the leaves and deepening of the sinuses.

SECONDARY EFFECTS:

24 TOXICITY:

Summary:

Slightly to moderately toxic.

Details:

Mammalian toxicity

Acute oral LD50 BEE - 713-803 mg/kg (rats), [For comparison table salt is 3000 mg/kg]

Acute dermal LD50 BEE - > 2000 mg/kg (rabbit).

Skin - BEE not irritating. BEE sensitising.

Eye - BEE minimal irritating.

Vapour inhalation - LC50 BEE - > 4.8 mg/L air (rat).

Chronic oral toxicity NOEL - 2.5-10 mg/kg/day for 183 days to 1 year (dogs).

Not mutagenic.

Classified as a Group D chemical i.e. not classifiable as to human carcinogenicity.

Not teratogenic at levels < 5 mg/kg/day (i.e. does not cause reproductive problems).

Other Species -

Birds - Low toxicity.

Fish - Low to moderate toxicity LC50 >3.46 mg/L to 144 mg/L.

Invertebrates - toxicity.

Bees - Practically non toxic. LD50 >100 ug/bee

Amphibians - Not acutely toxic.

Insects - Slightly toxic.

25 TOXICITY SYMPTOMS:

26 FIRST AID:

27 ENVIRONMENTAL FATE:

Triclopyr is broken down mainly by microbial activity in soil.

It has a half life in soil of 10-46 days.

It has a half life in water of 3.7-4.7 days 1312.

It has an EPA classification for soil mobility that ranges from

Ground water contamination

Replanting intervals are less than 12 months.

Accumulation in milk and tissues.

No adverse effects on water quality or on the non-target biotic community are expected following triclopyr applications 1313,1312.

28 REGISTERED CROPS:

See HerbiGuide Species Solution tab.

29 REGISTERED WEEDS:

See HerbiGuide Species Solution tab.

30 REGULATION AND LEGAL:

UN number:

CAS numbers: 64700-56-7

OPP Chemical Code: 116004

Hazchem code:

NOHSC classification:

Land transport:

Dangerous goods class (ADG):

Sea transport:

Proper shipping name:

International Maritime Dangerous Goods Code (IMDG):

Class:

Packaging group:

EPG:

Risk phrases:

31 PROPERTIES:

Triclopyr technical is a colourless odourless solid.

Colour: Light brown.

Odour: Hydrocarbon.

Form: Oil soluble liquid.

Chemical name:

Empirical formula: C13H16Cl3NO4

IUPAC

CAS: 64700-56-7

Water solubility: 430 mg/L at 25 C at pH 7;

Oil solubility: Very soluble in ethanol, slightly soluble in benzene.

Octanol:Water ratio: LogPow = at 25 C at pH 5;

Soil organic carbon absorption coefficient (Koc):

Vapour Pressure: 1.26 x 10-6 mm Hg at 25 C.

Vapour density:

Dissociation constant: pKa

Melting point: 148-150 C. Decomposes at 2900C.

Boiling point: C.

Molecular weight: 356.6g for BEE.

Bulk density:

Specific gravity:

pH:

Flammability:

Flashpoint: C.

Autoignition: C.

Corrosivity:

Shelf Life: years.

(When Stored under Ideal Conditions)

The ester formulations are usually more active than the amine formulations.

32 SPILLS:

Extinguish possible sources of ignition.

Absorb spill with earth, sand, clay or absorbent material.

Ventilate area after cleanup.

33 FIRE:

Extinguish with water spray, foam, carbon dioxide or dry agent.

Toxic fumes may be released in fire. Wear breathing apparatus or avoid smoke.

34 COMMENTS:

35 REFERENCES:

Watson, K.L. (1978). Proceedings of the First Conference of the Council of Australian Weed Science Societies, Melbourne, April 1978. P67-70.

Acknowledgments:

Collated by HerbiGuide. For more information see www.herbiguide.com.au or phone 08 98444064.