Indoxacarb

1. Trade Name 2. Manufacturer3. Formulation
DUPONT AVATAR INSECTICIDEDU PONT (AUSTRALIA) LTDWG
DUPONT STEWARD EC INSECTICIDEDU PONT (AUSTRALIA) LTDEC

4. ACTIVE INGREDIENTS: Indoxacarb 300g/kg or 150g/L

5. COST: $280.00 per L or kg.

6. CHEMICAL GROUP: 22A.

7. RELATED PESTICIDES:

Indoxacarb 300g/kg or 150g/L

8. GENERAL DESCRIPTION:

An agricultural and horticultural insecticide for the control of insects mainly from the Lepidoptera (caterpillar) family and weevils. It is relatively soft beneficial insects such as predatory beetles, trnavers ladybirds, ants and pirate bugs. It has little action on spiders and lacewings.

9. APPLICATION METHODS AND TIPS:

Best results usually come from cosecutive applications up to the maximum allowed before switching to another group.

Ensure thorough and even coverage.

Add directly to water in the tank and don't premix as a slurry.

Keep agitated. Air agitation is not recommended.

Use wettable granule formulations immediately, as it tends to settle and my be difficult to resuspend. Use EC formulations within 72 hours of mixing.

Add a non-ionic wetting agent but don't use wetting agent when mixing with liquid feriliser. Agral or Citowet preferred as BS1000 or Activator 90 may cause damage to vegetable and fruit crops.

Do not apply within 20 m upwind of water bodies.

Do not use on glashouse, greenhouse, hydroponic or container grown fruit and vegetables.

Avoid drift onto grazing land.

For export crops, check with exporter that MRLs are in place for the country of destination.

10. ADJUVANTS, WETTERS, OILS:

None recommended.

11. EQUIPMENT:

High volume and low volume sprayers, boom sprays and hand leads. Ensure thorough and even coverage. Ensure at least 60 droplets per square centimetre.

Use droplets with a VMD of 150-200 micron to help reduce drift.

275 kPa (40psi) is the minimum recommended pressure for flat fan nozzles on the label. Pressures above 200 kPa (30 psi) are adequate.

12. SPRAYER WASH OUT AND DECONTAMINATION:

Clean Up:

Clean soon after spraying to reduce the risk of forming dried deposits that may be difficult to remove.

Remove filters and clean separately. Rinse with soapy water (eg 500 mL or g of Drive, Dynamo, Omo or Surf per 100 L water) or water plus 0.25% wetting agent and run through boom. Rinse with water.



Decontamination:

Remove filters and clean then soak in 500 mL household ammonia in 10 L water for 30 minutes.

Rinse sprayer with soapy water (eg 500 mL or g of Drive, Dynamo, Omo or Surf per 100 L water) or water plus 0.25% wetting agent and run through boom. Fill with 1% solution of ammonia and allow to stand for several hours. Triple rinse with water. Or use a commercial spray tank and equipment cleaner.

Rinse nozzles and filters in water and replace.

13. WATER OR CARRIER DATA:

Use clean water.

100 - 1500 L/ha for ground sprays.

30 L/ha for aerial application.

If using low carrier volumes select nozzles to provide at least 50 droplets per square centimeter.

14. WEATHER:

Apply in fine weather at least 2 hours before rain.

Don't apply if there is heavy dew on the crop.

Avoid applications during inversion conditions or when winds are less than 2 kph or greater than 25 kph.

15. RAINFASTNESS:

2 hours

16. SOIL:

No particular effect.

17. PLANT HEALTH and OTHER EFFECTS:

Some adjuvants such as BS1000 and Activator 90 may cause damage on some fruit and vegetable crops.

18. WITHHOLDING PERIODS:

Harvest

Cotton - 28 days.

Adzuki Beans, Chickpeas, Faba Beans, Mung Beans, Soybeans - 21 days.

Capsicum, Eggplant, Leafy vegetables, Peppers, Tomatoes - 3 days.

Apricot, Brocolli, Brussl Sprouts, Cabbage, Cauliflower, Nectarine, Peach, Plum - 7 days.

Apples, Nashi Pears, Pears - 14 days.

Grapes - 8 weeks. Do not use treated grape leaves for human consumption.

Gazing

Adzuki Beans, Chickpeas, Faba Beans, Mung Beans, Soybeans - 21 days.

Do not graze other treated crops or vegetable waste except Tomato pomace.

Do not graze or feed cotton stubble or gin trash.

Export Slaughter Interval - 28 days.

Harvest

Cotton - 28 days.

Adzuki Beans, Chickpeas, Faba Beans, Mung Beans, Soybeans - 21 days.

Capsicum, Eggplant, Leafy vegetables, Peppers, Tomatoes - 3 days.

Apricot, Brocolli, Brussl Sprouts, Cabbage, Cauliflower, Nectarine, Peach, Plum - 7 days.

Apples, Nashi Pears, Pears - 14 days.

Grapes - 8 weeks. Do not use treated grape leaves for human consumption.

Gazing

Adzuki Beans, Chickpeas, Faba Beans, Mung Beans, Soybeans - 21 days.

Do not graze other treated crops or vegetable waste except Tomato pomace.

Do not graze or feed cotton stubble or gin trash.

Export Slaughter Interval - 28 days.

19. PLANT BACK PERIODS or RECROPPING INTERVALS:

20. MODE OF ACTION:

An oxadiazine insecticide. It is a sodium channel antagonist.

Acts primarily as a larvacide.

It acts mainly on larvae by ingestion of treated foliage though there is some absrption through the insect cuticle.

Larvae cease feed soon after ingesting indoxocarb and die 3-5 days later.

21. PESTICIDE RESISTANCE:

Some species may be resistant or develop resistance with continued application. Rotate with products from alternative groups.

It is expected to control insects resistant to other groups of insecticdes and no cross resitance has been reported.

22. TOXICITY:

Poison schedule - S6

Summary: Hazardous if swallowed. May irritate eyes, skin and respiratory tract.

Details:

Poison schedule - S6

Mammalian toxicity -

Acute oral LD50 - 687-1867 mg/kg (rats), [For comparison table salt is 3000 mg/kg] Hazardous if swallowed

Acute dermal LD50 - >5000 mg/kg (rabbit).

Skin - May cause slight skin irritation with itching, redness and swelling. Not a skin sensitiser.

Eye - May cause mild irritation with tearing and blurred vision. Active is not irritating.

Vapour inhalation - LC50 - >5.2 mg/L air (rat). May cause irritation of upper respiratory system and coughing.

Chronic oral toxicity NOEL - ppm for two years.

Not mutagenic or teratogenic (i.e. does not cause cancer or reproductive problems).

Acceptable Daily Intake (ADI) -

Noel - 40 ppm (Dogs). 25-100 ppm for rats.

23. TOXICITY SYMPTOMS:

Nasal discharge, altered righting reflex, incoordination, tremours and convulsions.

May cause anemia or alteration in blood cell counts, slight skin irritation with itching, redness and swelling and may cause mild eye irritation with tearing and blurred vision and may cause irritation of upper respiratory system and coughing.

24. FIRST AID:

If SWALLOWED - Do not induce vomitting unless advised by doctor. Give a glass of water to sip. Don't give anything by mouth to an unconscious person. See a Doctor.

If in EYES - Irrigate for 15 minutes with plenty of water. If eye irritation persist then see a Doctor.

If on SKIN - Rinse with plenty of water, remove contaminated clothing, wash with soap and water.

If INHALED - Remove patient to fresh air.

If patient has symptoms or is concerned contact a doctor immediately.

Advice to doctor - Treat symptomatically.

Call Poisons Information Centre on 13 11 26

25. PROTECTIVE CLOTHING:

Safety goggles and face shield.

Elbow length PVC gl;oves.

Cotton overalls and washable hat.

Boots.

26 RE ENTRY PERIODS and OTHER SAFETY ISSUES:

Where protective clothing (cotton overalls, hat, boots and gloves) if working in the sprayed area before the spray has dried.

27. PROPERTIES:

Product appearance - Water dispersible dark brown granule or amber liquid formulations.

Odour - Mild lignin or burnt sugar.

Shelf Life -

Product Flammability - Non flammable. Flashpoint >100 C. Not explosive.

Half life in water - days at pH5 and 35 C.

Water solubility at 25 C. - 0.2 ppm for active. Product forms a suspension.

Oil solubility -

Octanol:Water ratio at 25 C. - at pH 5.

Vapour Pressure at 25 C. - 2.5 x 10-8 Pa for active

Dissociation constant - pKa.

Melting point - C.

Boiling point -

Molecular weight -

Density - 0.8 g/mL for granules. 0.947 g/cm3 at 25 C for liquid.

pH - 6.6 at 10 g/L

Viscosity 5.6 mPa/s at 25 C.

28. ENVIRONMENTAL FATE:

Summary - Toxic to bees and aquatic organisms.

Birds - Low to moderate toxicity. LD50 98 mga.i./kg (Bobwhite Quail). LC50 808 ppm (Bobwhite Quail) for a.i.

Fish - High toxicity. LC50 0.65-3.2 mg a.i./L (Rainbow trout).

Invertebrates - High toxicity. LC50 0.6 mg a.i./L.

Algae - Hogh toxicity. EC50(120hr) = 0.11 mg/L

Bees - High toxicity.

It has a half life in soil of .

It has an EPA classification for soil mobility that ranges from

Ground water contamination

Accumulation in milk and tissues. Does not bioaccumulate or persist.

29. COMPATIBILITY:

See HerbiGuide for compatability with other herbicides, insecticides and fungicides.

See HerbiGuide for a full list of pesticide compatibilities.

Not compatible with Supa K 30, Zip or Triple 7.

30. REGISTERED CROPS, INSECTS and DISEASES.

See Herbiguide Species Solutions Tab for registered uses.

31. GOVERNMENT AND REGULATORY INFORMATION:

Dangerous Goods Class - Not clasified as a dangerous good

Hazchem Code -

Packaging Group - III

Initial Emergency Response Guide IERG -

UN Number - 3082

NOHSC Classification and phrases - Hazardous if swallowed.

CAS Number - 173584-44-6

Proper Shipping Name - Environmentally hazardous substance, liquid, n.o.s. (Indoxacarb)

Class - 9

Marine pollutant.

32. References:

Avatar label and msds 2008. Steward MSDS 27/8/2007.

Acknowledgments:

Collated by HerbiGuide. Phone 08 98444064 for more information.