Lontrel

Lontrel

1 Trade name	Manufacturer	Form
4FARMERS CLOPYRALID 300 SELECTIVE HERBICIDE	4 FARMERS PTY LTD	AC
AC CARNAGE 300 HERBICIDE	AXICHEM PTY LTD	AC
AGRISMART CLOPYRALID 300 HERBICIDE	GOOBANG PTY LTD	AC
AGROREG CLOPYRALID 300 SL HERBICIDE	AGROREG PTY LIMITED	SL
AW CLASH 300 HERBICIDE	AGRI WEST PTY LIMITED	AC
CLOCK 300 HERBICIDE	GROW CHOICE PTY LIMITED	AC
CMS CLOPYRALID 300 SL HERBICIDE	CMS TRADE PTY LTD	SL
CONQUEST CORSAIR HERBICIDE	CONQUEST CROP PROTECTION PTY LTD	AC
COUNTRY CLOPYRALID 300 SELECTIVE HERBICIDE	ACCENSI PTY LTD	SL
FARMOZ VICTORY HERBICIDE	FARMOZ PTY LIMITED	SL
GENEREX CLOPYRALID HERBICIDE	MACSPRED PTY. LTD.	AC
GENFARM CLOPYRALID 300 HERBICIDE	LANDMARK OPERATIONS LIMITED	AC
HALLEY CLOPYRALID HERBICIDE	HALLEY INTERNATIONAL ENTERPRISE (AUSTRALIA) PTY LTD	AC
KENSO AGCARE KEN-TREL 300 HERBICIDE	KENSO CORPORATION (M) SDN. BHD.	AC
LONTREL HERBICIDE	DOW AGROSCIENCES AUSTRALIA LIMITED	AC
NUFARM ARCHER HERBICIDE	NUFARM AUSTRALIA LIMITED	AC
OSPRAY SPARTA 300 SL HERBICIDE	OSPRAY PTY LTD	AC
OZCROP CLOPYRALID 300 SL HERBICIDE	CMS TRADE PTY LTD	SL
PACIFIC CLOPYRALID 300 HERBICIDE	PACIFIC AGRISCIENCE PTY LTD	SL
RALLY HERBICIDE	IMTRADE AUSTRALIA PTY LTD	AC
SMART CLOPYRALID 300 HERBICIDE	CROP SMART PTY LTD	AC
SYLON 300 HERBICIDE	SIPCAM PACIFIC AUSTRALIA PTY LTD	SC
TITAN CLOPYRALID 300 HERBICIDE	TITAN AG PTY LTD	AC
TRANSIT HERBICIDE	CROP CARE AUSTRALASIA PTY LTD	AC
UNITED FARMERS CLOPYRALID HERBICIDE	RAVENSDOWN FERTILISER CO-OPERATIVE LIMITED	AC
UNI-VERT 300 SELECTIVE HERBICIDE	UNITED PHOSPHORUS LTD.	SL

2 PRICE:

$25.3

3 ACTIVE INGREDIENTS: Clopyralid 300g/L

4 CHEMICAL GROUP: I.

Disrupter of plant cell growth.

5 RELATED HERBICIDES:

2,4-D amine 500	2,4-D Amine 500g/L
2,4-D amine 625	2,4-D Amine 625g/L
2,4-D amine plus Dicamba	2,4-D 250gL + dicamba 100g/L
2,4-D ester 800	2,4-D Ester 800g/L
2,4-D ester plus Garlon	2,4-D ester 530g/L + triclopyr 200g/L
2,4-D LV ester 600	2,4-D LV ester 600-680g/L
2,4-DB 400	2,4-DB 400g/L
2,4-DB plus MCPA	2,4-DB 200g/L + MCPA 250g/L
Access	Picloram 120g/L + triclopyr 240g/L
Dicamba 200	Dicamba 200
Dicamba 25 plus MCPA 150	Dicamba 25g/L + MCPA 150g/L
Dicamba 500	Dicamba 500g/L
Dicamba 700	Dicamba 700g/kg
Dicamba plus MCPA	Dicamba 80g/L + MCPA 340g/L
Garlon 600	Triclopyr 600g/L
Grazon Extra	Aminopyralid 8g/L+picloram 100g/L+tricolpyr 300g/L
Hotshot	Aminopyralid salt 10g/L + fluroxypyr-meptyl 140g/L
Lontrel	Clopyralid 300g/L
Lontrel 750	Clopyralid 750g/kg
MCPA amine	MCPA 500-750g/L
MCPA LVE	MCPA LV ester 500g/L
MCPB 400	MCPB 400g/L
Picloram plus Triclopyr	Picloram 100g/L + triclopyr 300g/L
Starane 200	Fluroxypyr 200-400g/L
Tordon 242	MCPA 420g/L + picloram 26g/L
Tordon 75-D	2,4-D 300g/L + picloram 75g/L
Tordon DS	Picloram amine 100g/L + triclopyr amine 200g/L
Tri-kombi	24D Ester 800g/L + Dicmaba 40g/L + Mecoprop 336g/L

6 GENERAL DESCRIPTION:

A selective, translocated herbicide for the control of a range of broad-leaved weeds in cereals and Brassica crops.

7 APPLICATION METHODS AND TIPS:

Best results when applied to young actively growing plants in fine weather and rain follows a few days later.

8 WEATHER:

Rainfast in hours.
Frost effects:
Wind:
Inversions:
Temperature:
Delta T and relative humidity: Avoid application when Delta T is greater than

9 ADJUVANTS:

Wetting agents:
Spray oils:

10 WATER QUALITY:

Hard water: There may be a slight loss of activity due to ionic bonding in very hard water.
Salty water:
Colloids: Some loss of activity as the amount of clay in the water increases. If it is difficult to see a coin on the bottom of a 10 litre bucket full of water then the water should be cleared or an alternate source found.
pH: Acidic water is usually OK. Highly alkaline water may cause loss of efficacy.
Tank life: 1 week.

11 COMPATIBILITY:

Trace elements: Zinc sulphate and copper sulphate are antagonistic with clopyralid. This is caused by ionic reactions and results in a significant loss of efficacy. Manganese sulphate and calcium carbonate (lime) have lesser effects.
See HerbiGuide Compatibilities button.

12 EQUIPMENT:

13 SPRAYER DECONTAMINATION:

14 HERBICIDE RESISTANCE:

Some plants are resistant.

15 REPLANTING INTERVALS:

Crop	Rates < 300 mL/ha	300- 500 mL/ha	Rates > 500 mL/ha
Bean; Faba	9 months	12 months	2 years
Chickpea	9 months	12 months	2 years
Clover	9 months	12 months	2 years
Lentil	9 months	12 months	2 years
Lucerne	9 months	12 months	2 years
Medic	9 months	12 months	2 years
Pea; Field	9 months	12 months	2 years
Safflower	9 months	12 months	2 years

16 WITHHOLDING PERIODS:

Crop	Type	Time
All	Harvest
All	Grazing

17 RE-ENTRY PERIOD:

18 PROTECTIVE CLOTHING:

19 SOIL:

20 MODE OF ACTION:

Disrupts cell growth by mimicking plant hormones.

Uptake and translocation:

Absorbed mainly through the foliage with some root absorption. Translocated strongly throughout the plant.

Physiological effects:

Residual Life and Breakdown:

21 SELECTIVITY:

Crop tolerance:

Varietal sensitivities:

Effect on Clover Species:

Effect on Medic Species:

Effect on Lucerne:

Effect on Native Plants:

22 DISEASE AND INSECT EFFECTS:

23 PLANT SYMPTOMS:

Distortion of young growth followed by death. The symptoms may be slow to appear and plants may take weeks to months to die.

SECONDARY EFFECTS:

Residues in the stubble of crops may affect plants in the following season.

24 TOXICITY:

Summary:

Low toxicity.

Details:

Poison schedule - S5
Mammalian toxicity - Low
Acute oral LD50 - > 4000 mg/kg (rats), [For comparison table salt is 3000 mg/kg]
Acute dermal LD50 - > 2000 mg/kg (rabbit).
Skin - Not irritating.
Eye - Mild irritant.
Vapour inhalation - LC50 - > mg/L air (rat).
Chronic oral toxicity NOEL - 50 mg/kg/day.
Not mutagenic or teratogenic (i.e. does not cause cancer or reproductive problems).
Acceptable Daily Intake (ADI) -

Other Species -

Birds - low toxicity.
Fish - low toxicity LC50 > ppm.
Invertebrates - low toxicity.
Bees - low toxicity.
Arthropods: toxicity.
Earthworms:

25 TOXICITY SYMPTOMS:

26 FIRST AID:

If SWALLOWED - No treatment is usually required. Contact the Poisons Information Centre on 13 11 26.
If in EYES - Irrigate with plenty of water.
If on SKIN - Rinse with plenty of water, remove contaminated clothing, wash with soap and water.
If INHALED - Remove patient to fresh air.
Advice to doctor - Treat symptomatically.
Contact the Poisons Information Centre on 131126.

27 ENVIRONMENTAL FATE:

Break down is by microbial action and is greatest in warm, moist, aerated soils with high organic matter.
It is not broken down in water by sunlight or hydrolysis.
Minimal leaching occurs and residues typically remain in the top 15 cm of soil
Accumulation in milk and tissues

Half life in soil: 12-70 days.
Half life in water: days at pH5 and 35 C.
It has an EPA classification for soil mobility that ranges from low to moderate.
Ground water contamination
Accumulation in milk and tissues: - does not accumulate
pH stability:
Photolysis rate: Very slow.
Hydrolysis half life: Very slow.
Biodegradation rate:

28 REGISTERED CROPS:

See HerbiGuide Species Solution tab.

29 REGISTERED WEEDS:

See HerbiGuide Species Solution tab.

30 REGULATION AND LEGAL:

UN number:
CAS numbers:
Hazchem code:
NOHSC classification:
Land transport:
Dangerous goods class:
Sea transport:
Proper shipping name:
Class:
Packaging group:
EPG:

31 PROPERTIES:

Empirical formula:
Water solubility: mg/L at 25 C at pH ;
Oil solubility:
Octanol:Water ratio: LogPow = at 25 C at pH 5;
Soil organic carbon absorption coefficient (Koc):
Vapour Pressure: at 25 C.
Dissociation constant: pKa
Melting point: C.
Boiling point: C.
Molecular weight:
Colour:
Odour:
Bulk density:
Specific gravity:
pH:
Flammability:
Shelf Life: years.
(When Stored under Ideal Conditions)

32 COMMENTS:

33 REFERENCES:

Ashton, F.M. and Crafts, A.S. (1981) Mode of Action of Herbicides. (Wiley-Interscience publication).

Kearney, P.C. and Kaufman, D.D. (1976). Herbicides. Chemistry, degradation and mode of action. Vol 1 & 2.

2. Concentration of Active Constituent : 300 g/L
3. Formulation : Aqueous Concentrate
4. Poison Schedule : 5
5. Trade name : Lontrel L - DowElanco
6. Product Colour : Straw colour.
7. Product Flammability : Non-flammable.
8. Dangerous Goods Class :
9. Shelf Life : 24 months
(When stored under ideal conditions- refer Page 4)
10. Mixtures Compatibility : 2,4-D, Glean (chlorsulfuron), MCPA, Aryloxyphenoxy grass killers eg Verdict.
Do NOT mix with :- Products that are highly alkaline/acidic or that contain high ion contents.
11. Registered Crop(s) : Wheat, Barley, Oats, Triticale, Canola, Pasture.
12. Effect of Soil Texture on Herbicide : Generally more mobile on soils of light texture and low organic matter.
13. Effect of Soil pH on Herbicide : Not available.
14. Effect of Soil Organic Matter on Herbicide : Generally more mobile on soils of light texture and low organic matter.
15. Mode of Action : Foliage translocation, some root absorption, Post-emergent.
16. Timing Application : Cereals - from 4 to 5 leaf stage.
17. Rate Variations : 50 mL - 4.0 L/ha
18. Rates Selection : Plant size generally determines the rate eg smaller plants, lower rates. 50 - 70 mL/ha should only be used in mixture with MCPA amine or LVE Ester. Lower water rates - only when crop canopy is open and there is no shielding of weeds by the crop. Higher water rate in dense crops to achieve better penetration and coverage.
19. Crop Damage (Crop Tolerance) : Wheat, Canola at 4-5 leaf stage. Clover and Medics - Nil tolerance.
21. Effect on Legume Species : Both sub clover and medics do not tolerate higher rates of Lontrel (300 mL/ha). 50 mL Lontrel + 1.0 L/ha MCPA is damaging to sub clover but only marginally more than 1.0 L/ha MCPA alone. Medics do not tolerate this mixture.
21c. Effect on Lucerne : Established plants are moderately to highly sensitive. Symptoms include yellowing, leaf cupping, retarding of growth and death.
22. Soil Moisture at Application : For optimal results plants should be actively growing.
23. Frost Effects : Lontrel L generally works more slowly under cool conditions.
25. Effect of Application Water Quality on Herbicide :
Saline Water - Lontrel L is formulated to tolerate a range of hard and soft water conditions.
Soil Colloids - Clean water is preferred.
26. Recommended Water Volume : 50 - 150 L/ha boom, 200 - 250 L/ha hardhead thistle, 10 - 50 L/ha aircraft, crop and pasture.
27. Nozzle Type : 110o flat fan, operating height 40 - 50 cm.
28. Recommended Nozzle Pressure : 200 - 350 kPa (28.6 - 50.8 psi).
30. Recommended Wetter : Not necessary for broadleaf weed control in cereals and oilseed rape (canola). The addition of a wetting agent is recommended for treatment of Hardhead and Californian thistles in pasture and fallow.
31. Other Additives : BP Ulvapron (Only in forestry situations). Synertrol is NOT recommended. Uptake, D-C-Trate, D-C-Tron, Hasten and BS 1000 are compatible.
32. Rain Fastness : Minimum 3 hours.
33. Time Interval Before Effect is Noticed : Depends upon the rate of plant growth, varies from hours to days/weeks.
36. Withholding Period : Do not graze, cut or harvest:-Pasture or cereals for 7 days, if sprayed with rates of 300ml/ha or less, Pasture or cereals for 28 days, when treated at rates in excess of 300ml/ha, Cereals for 70 days, when treated at rates in excess of 300ml/ha, Canola for 84 days after application.
37. Plant-Back Period : Lupins, Field Peas - 9 months when treated at rates of 300 - 500 mL/ha. Clovers, Medics - Minimum 12 months when treated at rates of 2 - 4 L/ha. (See above for updated data)
38. Spray Tank Clean-Up : Wash out with hot soapy water or 1% solution of ammonia followed by several rinses with clean water.
39. Other Comments : Avoid spray drift onto susceptible crops or plants such as lupins, faba beans, field peas, vines, fruit trees, vegetables and ornamentals. The rate of clopyralid decay is affected by both soil texture and rainfall in the period following application. Clopyralid residues in canola or cereal stubble may cause damage to susceptible crops grown in rotation the following season. These crops include: field peas, faba beans, lupins, chickpeas, and sub clover or medic pastures (volunteer or undersown). Accordingly rotations should be planned to ensure these crops/pastures will not be grown in the year following the use of Lontrel L in cereal or canola crops. Corrosive to aluminium, steel and tin plate.
Numbered data from "Crop Herbicide Information"
Courtesy of A.J. Chambers, Vic. Dept of Food & Agric.

Acknowledgments:

Collated by HerbiGuide. For more information see www.herbiguide.com.au or phone 08 98444064.