Mandestrobin

1_Trade_NameManufacturerForm
INTUITY FUNGICIDESUMITOMO CHEMICAL AUSTRALIA PTY LIMITEDSUSPENSION CONCENTRATE

4. ACTIVE INGREDIENTS: Mandestrobin 250g/L

5. COST: $300.00 per L or kg.

6. CHEMICAL GROUP: 11.

7. RELATED PESTICIDES:

Azoxystrobin 250g/L (95 to 500g/L forms)
BACILLUS THURINGIENSIS SSP. KURSTAKI SC
BACILLUS THURINGIENSIS SSP. KURSTAKI WG
Mandestrobin 250g/L
Trifloxystrobin 500g/L

8. GENERAL DESCRIPTION:

Mandestrobin is an agricultural fungicide for control of diseases such as Blossom Blight and Brown Rot in orchards. It is harmless to predators of mites and suiable for use in IPM programs.

9. APPLICATION METHODS AND TIPS:

Best results in fine weather.
Ensure thorough coverage.

10. ADJUVANTS, WETTERS, OILS:

A non-ionic wetting agent may improve control.

11. EQUIPMENT:

High volume sprayers are preferred.

12. SPRAYER WASH OUT AND DECONTAMINATION:

13. WATER OR CARRIER DATA:

Spray to run-off for Hi Vol applications.

14. WEATHER:

Do not apply if heavy rain is forecast.
Do not apply during inversion conditions.

15. RAINFASTNESS:

2 hours

16. SOIL:

No effect.

17. PLANT HEALTH and OTHER EFFECTS:

18. WITHHOLDING PERIODS:

Don't graze treated areas.
Harvest: stone fruit 7 days.
Export harvest interval - Contact Sumitomo.
Don't graze treated areas.
Harvest: stone fruit 7 days.
Export harvest interval - Contact Sumitomo.

19. PLANT BACK PERIODS or RECROPPING INTERVALS:

20. MODE OF ACTION:

Protectant.
Group 11 member of the Quinone outside Inhibitor (QoI) group of fungicides

21. PESTICIDE RESISTANCE:

Some species may be resistant or develop resistance with continued application. Rotate with products from alternative groups.

22. TOXICITY:

Poison schedule - S5
Summary: Low toxicity.
Details:
Poison schedule - S5
Mammalian toxicity -
Acute oral LD50 - >3129mg/kg (rats), [For comparison table salt is 3000 mg/kg]
Acute dermal LD50 - >5000 mg/kg (rabbit).
Skin - Mildy irritating. Non-sensitizer
Eye - May be slightly irritating.
Vapour inhalation -May be harmful if inhaled. LC50 - >2.04 mg/L air (rat).
Chronic oral toxicity NOEL - ppm for two years.
Not mutagenic or teratogenic (i.e. Does not cause cancer or reproductive problems).
Acceptable Daily Intake (ADI) -

23. TOXICITY SYMPTOMS:

24. FIRST AID:

If SWALLOWED - Do NOT induce vomiting unless directed by doctor. Rinse mouth with water.
If in EYES - Irrigate for 15 minutes with plenty of water.
If on SKIN - Rinse with plenty of water, remove contaminated clothing, wash with soap and water. Wash off with polyethyleneglycol 400 if available then rinse with water.
If INHALED - Remove patient to fresh air.
If patient has symptoms or is concerned contact a doctor immediately.
Advice to doctor - Treat symptomatically. No specific symptoms known or expected. No specific antidote.
Gastric lavage is not normally required. However, if a significant amount (more than a mouthful) has been ingested, administer activated charcoal and sodium sulphate.
Call Poisons Information Centre on 13 11 26

25. PROTECTIVE CLOTHING:

Safety goggles and face shield.
Elbow length PVC gl;oves.
Cotton overalls and washable hat.
Boots.

26 RE ENTRY PERIODS and OTHER SAFETY ISSUES:

After spray has dried.

27. PROPERTIES:

Product appearance - White opaqueliquid with no odour.
Shelf Life -
Product Flammability - Not flammable.
Half life in water - days at pH5 and 35 C.
Water solubility at 25 C. - Miscible
Oil solubility -
Octanol:Water ratio at 25 C. -
Vapour Pressure at 25 C. -
Dissociation constant - pKa.
Melting point - C.
Boiling point -
Molecular weight -
Density - 1.05 g/cm3 at 20C
Viscosity 1500-2000 mPa s @ 25°C
pH 6 to 8 at 100% at 23C.
Flashpoint > 100C.

28. ENVIRONMENTAL FATE:

Summary - Toxic to aquatic organisms.
Birds - Low toxicity
.Acute Oral LD 50 canary: greater than 2000 mg/kg bw
Acute Oral LD 50 bobwhite quail: greater than 2250 mg/kg bw
Acute Dietary LC 50 mallard duck: greater than 5620 ppm
Acute Dietary LC 50 bobwhite quail: greater than 5620 ppm
Reproduction bobwhite quail: NOEC = 1000 ppm
Reproduction mallard duck: NOEC = 1000 ppm
Fish - High toxicity
Acute LC 50 (96 hr) Bluegill Sunfish: 2.3 mg/L
Acute LC 50 (96 hr) Rainbow Trout: 0.94 mg/L
Acute LC 50 (96 hr) Sheepshead Minnow: greater than 2.2 mg/L
Invertebrates: High toxicity.
Acute EC 50 (48 hr) Daphnia magna: 1.2 mg/L
Acute LC 50 (96 hr) Mysid Shrimp: 0.43 mg/L
Algae: High toxicity.
Acute EC 50 (96 hr) Green algae: = 0.33 mg/L
Aquatic plants: Acute EC 50 (7 d) Duckweed: greater than 2.3 mg/L
Bees - Low toxicity.
Honeybee Acute Oral LD 50 : greater than 111 ug (microgram)/bee
Honeybee Acute Contact LD 50 : greater than 100 ug (microgram)/bee
It has a half life in soil of .
It has an EPA classification for soil mobility that ranges from
Not leached in soil.
Ground water contamination - unlikely
Accumulation in milk and tissues.
Does not bioaccumulate.

29. COMPATIBILITY:

See HerbiGuide for compatibility with other herbicides, insecticides and fungicides.
See HerbiGuide for a full list of pesticide compatibilities.

30. REGISTERED CROPS, INSECTS and DISEASES.

See HerbiGuide Species Solutions Tab for registered uses.

31. GOVERNMENT AND REGULATORY INFORMATION:

Dangerous Goods Class - Not a dangerous good.
Hazchem Code - 3Z
Initial Emergency Response Guide IERG -
CAS Number - Mandestrobin 173662-97-0
Propylene glycol 57-55-6
SWA Classification and phrases -
R-phrase(s)
S-phrase(s) -

ADG
UN number 3082
Class 9
Subsidiary Risk None
Packaging group III
Description of the goods: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (mandestrobin 25%)
Hazchem Code: 3Z

IMDG
UN number 3082
Class 9
Subsidiary Risk None
Packaging group III
EmS F-A , S-F
Marine pollutant YES
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (mandestrobin 25%)

IATA
UN number 3082
Class 9
Subsidiary Risk None
Packaging group III
Environm. Hazardous Mark
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (mandestrobin 25%)

32. References:

69787/61735 label & SDS 0216 (Pinpoint SDS Canada)

Acknowledgments:

Collated by HerbiGuide. Phone 08 98444064 or www.HerbiGuide.com.au for more information.