Quinclorac

1 Trade nameManufacturerForm
DRIVE HERBICIDEBASF AUSTRALIA LTD.WATER DISPERSIBLE GRANULE
DRIVE XL HERBICIDEBASF AUSTRALIA LTD.SOLUBLE CONCENTRATE
Quinstar 200SC HerbicideADAMA AUSTRALIA PTY LIMITEDSUSPENSION CONCENTRATE
STEER 750 HERBICIDETURF CULTURE PTY LTDWATER DISPERSIBLE GRANULE

2 PRICE:

$9999/kg
$9999/L

3 ACTIVE INGREDIENTS: Quinclorac 750g/kg (or180or200)

4 CHEMICAL GROUP: I

Carboxylic acid group of herbicides and disrupts plant cell growth.

5 RELATED HERBICIDES:

2,4-D amine 5002,4-D Amine 500g/L
2,4-D amine 6252,4-D Amine 625g/L
2,4-D amine plus Dicamba2,4-D 333g/L + dicamba 166g/L
2,4-D ester 8002,4-D Ester 800g/L
2,4-D ester plus Garlon2,4-D ester 530g/L + triclopyr 200g/L
2,4-D LV ester2,4-D LV ester 680g/L (or600)
2,4-DB 5002,4-DB 500g/L
2,4-DB plus MCPA2,4-DB 200g/L + MCPA 250g/L
AccessPicloram 120g/L + triclopyr 240g/L
Aminopyralid plus picloram gelAminopyralid 4.47g/L+picloram 44.7g/L
Dicamba 25 plus MCPA 150Dicamba 25g/L + MCPA 150g/L
Dicamba 500Dicamba 500g/L
Dicamba 700Dicamba 700g/kg (or 750 g/kg)
Dicamba plus MCPADicamba 80g/L + MCPA 340g/L
FallowBoss2,4-Dam 300g/L+Aminopyralid 7.5g/L+picloram 75g/L
Garlon 600Triclopyr 600g/L (or 755g/L)
Grazon ExtraAminopyralid 8g/L+picloram 100g/L+triclopyr 300g/L
HotshotAminopyralid salt 10g/L + fluroxypyr-meptyl 140g/L
LontrelClopyralid 300g/L
Lontrel 750Clopyralid 750g/kg
MCPA amineMCPA 500-750g/L
MCPA LVEMCPA LV ester 500g/L
MCPB 400MCPB 400g/L
PicloramPicloram 240g/L
Picloram plus TriclopyrPicloram 100g/L + triclopyr 300g/L
QuincloracQuinclorac 750g/kg (or180or200)
Starane 200Fluroxypyr 200-400g/L
Tordon 242MCPA 420g/L + picloram 26g/L
Tordon 75-D2,4-D 300g/L + picloram 75g/L
Tordon DSPicloram amine 100g/L + triclopyr amine 200g/L
Tordon RegrowthMasterAminopyralid 25g/L+picloram100g/L+triclopyr 200g/L
Tri-kombi24D Ester 800g/L + Dicamba 40g/L + Mecoprop 336g/L

6 GENERAL DESCRIPTION:

A post emergence, leaf absorbed, translocated, non residual herbicide applied as spray in water.

7 APPLICATION METHODS AND TIPS:

Best results on young actively growing weeds in fine weather.
Clippings from the first 3 mowings should be left on the treated area.
Do not apply if heavy rain is expected within 48 hours, or within 8 hours prior to irrigation.
Do not apply to golf course collars or greens or bowling greens.
Do not apply within 4 weeks after seedling emergence of Kentucky Bluegrass, Creeping Bentgrass and Perennial Ryegrass.
Add directly to tank. Do not make a slurry or paste before adding to tank. Keep agitated.
Do not apply within 4 weeks after seedling emergence of Kentucky Bluegrass, Creeping Bentgrass and Perennial Ryegrass.
Avoid mowing turf 2 days before or after spraying.
Avoid overlaps when spraying.
Do not apply through irrigation.
Can estimate weight for spraying by 5 times in measuring cylinder and then 1000 mL = 700 grams or 1100 grams = 1571 mL.

8 WEATHER:

Rainfast in hours .
Frost effects:
Wind:
Inversions: Don't apply during inversions
Temperature:
Delta T and relative humidity:

9 ADJUVANTS:

Wetting agents:
Spray oils: May improve weed control. Methylated seed oils preferred.

10 WATER QUALITY:

Hard water:
Salty water:
Colloids:
pH:
Tank life:

11 COMPATIBILITY:

Trace elements.
See HerbiGuide Compatibilities button.

12 EQUIPMENT:

Boom sprays:

Carrier volume: 400 L/ha on label. 100 L/ha or more should be OK.
Nozzles: Flat fan.
Pressure: 150-400 kPa.
Droplet size:

Aerial application:

Carrier volume:

13 SPRAYER DECONTAMINATION:


Clean Up:

Clean soon after spraying to reduce the risk of forming dried deposits that may be difficult to remove.
Remove filters and clean separately. Rinse with soapy water (e.g. 500 mL or g of Drive, Dynamo, Omo or Surf per 100 L water) or water plus 0.25% wetting agent and run through boom. Rinse with water.

Decontamination:

Remove filters and clean then soak in 500 mL household ammonia in 10 L water for 30 minutes.
Rinse sprayer with soapy water (e.g. 500 mL or g of Drive, Dynamo, Omo or Surf per 100 L water) or water plus 0.25% wetting agent and run through boom. Fill with 1 litre of 3% household ammonia per 100 litres of water and circulate for at least 15 minutes (allow to stand for several hours if possible). Triple rinse with water. Or use a commercial spray tank and equipment cleaner.
Rinse nozzles and filters in water and replace then rinse the whole system with water again.
Don't use chlorine based cleaners in combination with ammonia.

14 HERBICIDE RESISTANCE:

Tolerant plants are expected to occur and may dominate the weed population after repeated applications.

15 REPLANTING INTERVALS:

CropTime

16 WITHHOLDING PERIODS:

CropTypeTime
AllGrazing 
AllHarvest 

17 RE-ENTRY PERIOD:

Wear protective clothing if in contact with the crop before the spray has dried.

18 PROTECTIVE CLOTHING:

Overalls, boots and washable hat. Use gloves and face shield when handling the concentrate.

19 SOIL:

Soil texture:
Soil pH:
Soil organic matter:
Soil moisture at application:

20 MODE OF ACTION:

Carboxylic acid group of herbicides and disrupts plant cell growth.
It is a quinoline carboxylic acid derivative.

Uptake and translocation:

Leaf absorbed. Highly translocated.

Physiological effects:

Residual Life and Breakdown:

21 SELECTIVITY:

Crop tolerance:

May cause transient yellowing on turf.
Do not apply to Bahia grass (Paspalum notatum), Centipede grass (Eremochloa ophiuroides), Buffalo grass (Stenotaphrum secundatum), Kikuyu (Pennisetum clandestinum), Queensland Blue Couch (Digitaria didactyla), Carpet grass (Axonopus spp.) or lawns or turf where desirable clovers are present.
Do not apply to ornamental beds or to exposed feeder roots of trees and ornamentals. Be particularly careful within the drip line of these plants.
Do not apply to golf course collars or greens.

Varietal sensitivities:

Transient yellowing may occur on Bent grass and Hybrid Couch such as Santa Ana and may last for 20 days.

Effect on Clover Species:

Kills clover.

Effect on Medic Species:

Kills medics.

Effect on Lucerne:

Damages lucerne.

Effect on Native Plants:

Damages many broadleaved native species.

22 DISEASE AND INSECT EFFECTS:

23 PLANT SYMPTOMS:

Susceptible weeds usually die within 1-2 weeks of spraying.

SECONDARY EFFECTS:

24 TOXICITY:

Summary:

Irritates the eyes and skin.

Details:

SUSMP classification (Poison schedule): S5
Mammalian toxicity:
Acute oral LD50: >2000 mg/kg (rat), [For comparison table salt is 3000 mg/kg]
Acute dermal LD50: >2000 mg/kg (rabbit).
Skin: Sensitiser. Irritant. May cause allergic skin reaction. Symptoms may include itchiness and reddening of contacted skin but should disappear after exposure has finished.
Eye: Irritant. Symptoms may include stinging and reddening of eyes and watering which should stop after brief exposure. Excessive exposure may cause permanent damage.
Vapour inhalation: LC50 >5 mg/L air (rat).
Not carcinogenic, mutagenic or teratogenic in animal studies (i.e. does not cause cancer or reproductive problems in animal tests).
Chronic oral toxicity: NOEL mg/kg for two years.
Acceptable Daily Intake (ADI):

Other Species:

Birds: Not toxic. LD50 for mallard duck is >2000 mg/kg
Fish: toxicity LC50 >100 mg/L.
Invertebrates: LC50 (48hr, quinclorac) for daphnia is 113 mg/L..
Bees: Not toxic.
Arthropods: toxicity.
Earthworms:
Algae: EC50 > 100 mg/L.
Accumulation:

25 TOXICITY SYMPTOMS:

26 FIRST AID:

If SWALLOWED: Do NOT induce vomiting. Wash out mouth with water. Do NOT give anything by mouth to a semiconscious or unconscious patient.
If in EYES: Hold eyelids open and wash eyes with plenty of water for 5 minutes, remove contact lenses if present and wash for a further 10 minutes. See a doctor if symptoms persist.
If on SKIN: Remove contaminated clothing. Wash skin thoroughly with soap and water.
If INHALED: Remove patient to fresh air. See a doctor if symptoms persist.
Advice to doctor: Treat symptomatically.
Contact the Poisons Information Centre on 131126.

27 ENVIRONMENTAL FATE:

Half life in soil: biodegradable.
Half life in water: days at pH5 and 35 C.
It has an EPA classification for soil mobility that ranges from
It has a leaching index of . (for comparison, trifluralin is 0-1 and chlorsulfuron is 25-30).
Ground water contamination:
Accumulation in milk and tissues:
pH stability:
Photolysis rate:
Hydrolysis half life:
Biodegradation rate:
Bioconcentration factor (BCF):

28 REGISTERED CROPS:

See HerbiGuide Species Solution tab.

29 REGISTERED WEEDS:

See HerbiGuide Species Solution tab.

30 REGULATION AND LEGAL:

APVMA Numbers: 70424,
UN number: None allocated.
CAS numbers: 84087-01-4
OPP Chemical Code:
Hazchem code:
SWA classification:
Land transport: ADG
Dangerous goods class (ADG): Not a Dangerous Good
Sea transport: IMDG
International Maritime Dangerous Goods Code (IMDG): Not a Dangerous Good
Proper shipping name:
Technical Name:
Hazard Class:
ID Number: .
Packaging group:
EMS Number:
EPG:
Marine Pollutant:
Air transport: IATA/ICAO
Not a Dangerous Good
Proper Shipping Name:
Technical Name:
ID Number:
Packaging group:
Cargo Packing Instructions:
Passenger Packing Instructions:
Environmental Hazard:

Risk phrases:
R43, R36/38. May cause sensitisation by skin contact. Irritating to eyes and skin.
Safety phrases:
S22, S28, S24/25, S37/39. Do not breathe dust. After contact with skin, wash immediately with plenty of soap and water. Avoid contact with skin and eyes. Wear suitable gloves and eye/face protection.
 

GHS Signal word: WARNING.
HAZARD STATEMENT:
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H320: Causes eye irritation.
H335: May cause respiratory irritation.
PREVENTION
P102: Keep out of reach of children.
P261: Avoid breathing dusts.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash contacted areas thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves, protective clothing and eye or face protection.
RESPONSE
P362: Take off contaminated clothing and wash before reuse.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P333+P313: If skin irritation or rash occurs: Get medical advice.
P337+P313: If eye irritation persists: Get medical advice.
P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog.
STORAGE
P410: Protect from sunlight.
P403+P233: Store in a well-ventilated place. Keep container tightly closed.

31 PROPERTIES:

Colour: Light tan.
Odour:
Form: Granule.
Chemical name: Quinclorac
Empirical formula:
IUPAC:
CAS: 84087-01-4
Water solubility: dispersible at 25 C at pH
Oil solubility:
Octanol:Water ratio: LogPow = at 25 C at pH 5.
Soil organic carbon absorption coefficient (Koc):
Vapour Pressure: Negligible at 25 C.
Vapour density: Not applicable.
Dissociation constant: pKa
Melting point: 274 C.
Boiling point: Expected to decompose before boiling.
Molecular weight:
Bulk density: 0.7. Can estimate weight for spraying by 5 times in measuring cylinder and then 1000 mL = 700 grams or 1100 grams = 1571 mL.
Specific gravity:
Viscosity: CPS.
pH: 6.0-8.0 (1% in water).
Flammability: Does not burn
Flashpoint: Does not burn.
Autoignition: Does not burn.
Corrosivity:
Shelf Life: years.
(When Stored under Ideal Conditions)

32 SPILLS:

Sweep up spilled material. Avoid washing material into waterways.

33 FIRE:

Extinguish with water spray, foam, carbon dioxide or dry agent.
Toxic fumes may be released in fire. Wear breathing apparatus or avoid smoke.

34 COMMENTS:

35 REFERENCES:

Turf Culture 2017 Label 70424/109233
Turf Culture SDS 70424 March 2015

Acknowledgments:

Collated by HerbiGuide. For more information see www.herbiguide.com.au or phone 08 98444064.