Spinetoram

1_Trade_NameManufacturerForm
DELEGATE INSECTICIDEDOW AGROSCIENCES AUSTRALIA LIMITEDWATER DISPERSIBLE GRANULE
SUCCESS NEO INSECT CONTROLDOW AGROSCIENCES AUSTRALIA LIMITEDSUSPENSION CONCENTRATE
SUCCESS NEO INSECTICIDEDOW AGROSCIENCES AUSTRALIA LIMITEDSUSPENSION CONCENTRATE

4. ACTIVE INGREDIENTS: Spinetoram 120g/L (or 250g/kg)

5. COST: $395.78 per L or kg.

6. CHEMICAL GROUP: 5.

7. RELATED PESTICIDES:

Spinetoram 120g/L (or 250g/kg)
Spinetoram 250g/kg
Spinosad 120-480g/L
Spinosad 800g/kg
Spiroxamine 500g/L

8. GENERAL DESCRIPTION:

An agricultural insectide for the control of various caterpillars and thrips in orchards, vineyards, fruit, herbs, ornamentals and forestry.

9. APPLICATION METHODS AND TIPS:

Apply as a high or low volume spray ensuring good coverage.

10. ADJUVANTS, WETTERS, OILS:

Adjuvants are not normally required. A non-ionic wetting agent may be used on difficult to wet crops where the product is applied alone. Seek advice for adjuvant use in tank mixes.

11. EQUIPMENT:

Use equipment that provides good coverage. Use air blast equipment or nozzles that produce a medium droplet size. Downwind no spray zones of 10-140m for stock pasture apply.

12. SPRAYER WASH OUT AND DECONTAMINATION:

13. WATER OR CARRIER DATA:

Use clean water with a pH of 5-9.
Stable in the tank for 24-48 hours.
100 to 5000 L/ha water.

14. WEATHER:

Apply in fine weather.

15. RAINFASTNESS:

30 minutes

16. SOIL:

No specific effects

17. PLANT HEALTH and OTHER EFFECTS:

18. WITHHOLDING PERIODS:

1-14 days harvest. Do not graze treated areas. Export slaughter interval is 14 days.
1-14 days harvest. Do not graze treated areas. Export slaughter interval is 14 days.

19. PLANT BACK PERIODS or RECROPPING INTERVALS:

None specified.

20. MODE OF ACTION:

Group 5. Acetylcholine receptor antagonist.
Ingestion and contact activity.

21. PESTICIDE RESISTANCE:

Do not make moren 4 applications per season. Switch to another group after 2-3 consecutive sprays. Some species may be resistant or develop resistance with continued application. Rotate with products from alternative groups.

22. TOXICITY:

Poison schedule - S5
Summary: Low toxicity to mammals
Details:
Poison schedule - S5
Mammalian toxicity - Low toxicity.
Acute oral LD50 - >5000 mg/kg (rats), [For comparison table salt is 3000 mg/kg]
Acute dermal LD50 - >5000 mg/kg (rabbit).
Skin - Slightly irritating. Not sensitising. Not allergenic.
Eye - Irritates eyes. Corneal injury unlikely.
Vapour inhalation - LC50 - >5.28 mg/L air (rat).
Chronic oral toxicity NOEL - ppm for two years.
Not carcinogenic, mutagenic or teratogenic (i.e. does not cause cancer or reproductive problems).
Acceptable Daily Intake (ADI) -

23. TOXICITY SYMPTOMS:

24. FIRST AID:

If SWALLOWED -
If in EYES - Irrigate for 15 minutes with plenty of water.
If on SKIN - Rinse with plenty of water, remove contaminated clothing, wash with soap and water.
If INHALED - Remove patient to fresh air.
If patient has symptoms or is concerned contact a doctor immediately.
Advice to doctor - Treat symptomatically. No specific antidote.
Call Poisons Information Centre on 13 11 26

25. PROTECTIVE CLOTHING:

Safety goggles and face shield.
Elbow length PVC gl;oves.
Cotton overalls and washable hat.
Boots.

26 RE ENTRY PERIODS and OTHER SAFETY ISSUES:

27. PROPERTIES:

Product appearance - Grey granules. No Odour.
Shelf Life -
Product Flammability - Not combustible
Half life in water - days at pH5 and 35 C.
Water solubility at pH7. - 11-48 ppm at pH
Oil solubility -
Octanol:Water ratio at 25 C. - at pH 5.
Vapour Pressure at 25 C. - 2.1-5.3 x 10-5 Pa
Dissociation constant - pKa.
Melting point - C.
Boiling point -
Molecular weight -
Density -0.5 g/mL
pH - 8.7.

28. ENVIRONMENTAL FATE:

Summary - Highly toxic to quatic species
Birds -Non toxic. LD50>5000 mg/kg.
Fish - High toxicity LC50 ~1 ppm.
Invertebrates - high toxicity.
Insects - Toxic to parasitic wasps and predatory mites but not toxic to ladybirds or rove beetles.
Bees - High contact toxicity. (foliage is non toxic after 3 hours to several days)
Earthworms - Non toxic.
It has a half life in soil of 1-5 days in he field and 3-29 days in lab conditions.
It has an EPA classification for soil mobility that is low.
Ground water contamination - Not likely to contaminate groundwater.
Accumulation in milk and tissues. Moderately transferred to milk, eggs and tissues.
Koc = 500-2000.
Not readily biodegradable.
Photolysis half life in water <12 hours.
Aerobic half life in lab aquatic systems was 117-124 days and is expected to be < 1 day in water under field conditions.
No hydrolysis exected.

29. COMPATIBILITY:

See HerbiGuide for compatibility with other herbicides, insecticides and fungicides.
See HerbiGuide for a full list of pesticide compatibilities.

30. REGISTERED CROPS, INSECTS and DISEASES.

See HerbiGuide Species Solutions Tab for registered uses.

31. GOVERNMENT AND REGULATORY INFORMATION:

Dangerous Goods Class - Not a dnagerous good for land transport. Dangerous good for air and sea transport. Environmentally hazardous. Marine pollutant.
Hazchem Code -
Packaging Group - III Class 9.
Initial Emergency Response Guide IERG -
UN Number - 3077
CAS Number - Spinetoram J 187166-40-1. Spinetoram L 187199-15-0
NOHSC Classification and phrases -
Hazardous
R50/53 Very toxic to aquatic organisms, may cause long ter adverse effects in the aquatic environment.
S57 Use apropriate containment fo avoid environmental damage.
S61 Avoid release to the environment.

32. References:

Acknowledgments:

Collated by HerbiGuide. Phone 08 98444064 or www.HerbiGuide.com.au for more information.