Tebuconazole plus Trifloxystrobin

1_Trade_NameManufacturerForm
DEDICATE TURF FUNGICIDEBAYER CROPSCIENCE PTY LTDSUSPENSION CONCENTRATE
FARMALINX ZOMBIE FUNGICIDEFARMALINX PTY LTDSUSPENSION CONCENTRATE
SCORPIO ORNAMENTAL FUNGICIDEBAYER CROPSCIENCE PTY LTDSUSPENSION CONCENTRATE
YATES ZALETON DUAL ACTION SYSTEMIC FUNGICIDEBAYER CROPSCIENCE PTY LTDSUSPENSION CONCENTRATE

4. ACTIVE INGREDIENTS: Tebuconazole 200g/L + trifloxystrobin 100g/L

5. COST: $671.00 per L or kg.

6. CHEMICAL GROUP: 3,11.

7. RELATED PESTICIDES:

Tebuconazole 200g/L + trifloxystrobin 100g/L

8. GENERAL DESCRIPTION:

A systemic fungicide for control of a range of fungal leaf diseases in lawns and gardens. It has preventative, antisporulant and early curative action with leaf disease control for up to 6 weeks.
It contains a strobilurin and DMI active ingredient.

9. APPLICATION METHODS AND TIPS:

Best results when applied to actively growing crops in fine weather at least 48 hours before rain.
Ensure thorough coverage of leaves and stems. Apply at first sign of disease or as a protectant when disease risk is high.
Use mixed spray within 24 hours.
Application to stressed crops may give unreliable results. Use products with a different mode of action as follow up sprays.
Record details of application. No spray zones apply for aerial application.

10. ADJUVANTS, WETTERS, OILS:

None required.

11. EQUIPMENT:

Hand spray to the point of runnoff.
Boom spray with flat fan nozzles at 100-400 kpa producing a medium droplets.

12. SPRAYER WASH OUT AND DECONTAMINATION:

Use commercial boom cleaner.

13. WATER OR CARRIER DATA:

1000-4000 L/ha for high volume and hand sprays.
50-100 L/ha water recommended for boom spray.

14. WEATHER:

Apply in fine weather at least 48 hours before rain. Frosts before or after spraying may reduce disease control.

15. RAINFASTNESS:

16. SOIL:

No specific effect of soil type but if plant growth is reducded by waterlogging or dry soils conditions then results may be unreliable. reducing

17. PLANT HEALTH and OTHER EFFECTS:

Good crop safety on most plants.

18. WITHHOLDING PERIODS:

Harvest -
Grazing - Don't graze treated areas.
Harvest -
Grazing - Don't graze treated areas.

19. PLANT BACK PERIODS or RECROPPING INTERVALS:

20. MODE OF ACTION:

Preventative, early curative and antisporulant action. Relatively long lasting up to 6 weeks. Inhibits spore germintion and reduces spread.
Systemic and rapidly translocated
Combination of DMI(triazole) and strobilurin(pyrimidine) fungicide.

21. PESTICIDE RESISTANCE:

Some species may be resistant or develop resistance with continued application. Rotate with products from alternative groups.
Avoid applying more than 2-4 sprays per season.

22. TOXICITY:

Poison schedule - S5
Summary: Hazardous according to NOHSC criteria.
Details:
Poison schedule - S5
Mammalian toxicity -Practically non toxic
Acute oral LD50 - 2500 mg/kg (rats), [For comparison table salt is 3000 mg/kg]
Acute dermal LD50 - >4000 mg/kg (rabbit).
Skin - Not irritating. Not sensitising.
Eye - Not irritating
Vapour inhalation - Harmful. LC50 - >2.43 mg/L air (rat).
Chronic oral toxicity NOEL - ppm for two years.
Not carcinogenic, mutagenic, neurotoxic or teratogenic in tests. (i.e. does not cause cancer or reproductive problems).
Acceptable Daily Intake (ADI) -

Carcinogen Status:
SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.

23. TOXICITY SYMPTOMS:

No specific symptoms. No cases of human poisoning have been recorded.

24. FIRST AID:

If SWALLOWED - Harmful if undiluted product swallowed. Rinse mouth with water. Give water to drink. Do NOT induce vomiting. If vomiting occurs give more water and seek medical advice.
If in EYES - Irrigate for 15 minutes with plenty of water. Seek medical advice if irritation occurs.
If on SKIN - Not harmful. Rinse with plenty of water, remove contaminated clothing, wash with soap and water.
If INHALED - Not harmful. Remove patient to fresh air.
If patient has symptoms or is concerned contact a doctor immediately.
Advice to doctor - Treat symptomatically. No specific antidote. No recorded cases of human poisoning.
Call Poisons Information Centre on 13 11 26

25. PROTECTIVE CLOTHING:

Safety goggles and face shield.
Elbow length PVC gl;oves.
Cotton overalls and washable hat.
Boots.

26 RE ENTRY PERIODS and OTHER SAFETY ISSUES:

After spray has dried for low exposure activities or 6-10 days for high exposure activities,

27. PROPERTIES:

Product appearance - Off white liquid with a characteristic odour.
Shelf Life - 2-3 years.
Product Flammability - Not flammable. Combustible (C1). Not explosive. Flashpoint >100 C at 755 mmHg. Not an oxidizer. Use water for fires. Don't allow fire water to enter waterways.
Half life in water - days at pH5 and 35 C.
Water solubility at 25 C. - Miscible with water..
Oil solubility -
Octanol:Water ratio at 25 C. - LogPow Tebuconazole 3.7.
Vapour Pressure - kPa at 20 C.
Dissociation constant - pKa.
Melting point - C.
Boiling point -
Molecular weight -
Density - SG = 1.1 @ 20C.
Non corrosive.
pH - 6-8 at 100% w/v

28. ENVIRONMENTAL FATE:

Summary - Highly toxic to aquatic life.
Birds - Trifloxystrobin - Practically non toxic - LD 50 >2000 mg/kg.
Fish - Trifloxystrobin - High toxicity Oncorhynchus mykiss (rainbow trout): LC50 = 0.286 mg/L , 96 h Invertebrates - Highly toxic. Daphnia magna (Water flea): EC50 = 0.224 mg/L, 48 h
Bees - Trifloxystrobin - practically non toxic. Oral LD50 > 500 ìg/bee, Contact LD50 >1800 ìg/bee
Algae - Toxic to algae.
Earthworms - Slightly toxic to earthworms Eisenia foetida (earthworm): LC50 >1500 mg/kg, 14 d
Trifloxystrobin is stable in water and is not persistent in soil. .
Trifloxystrobin has low to very high mobility in soil. Trifloxystrobin is incorporated into organic molecules.
Ground water contamination
Accumulation in milk and tissues. .

29. COMPATIBILITY:

See HerbiGuide for compatibility with other herbicides, insecticides and fungicides.
See HerbiGuide for a full list of pesticide compatibilities

30. REGISTERED CROPS, INSECTS and DISEASES.

See HerbiGuide Species Solutions Tab for registered uses.

31. GOVERNMENT AND REGULATORY INFORMATION:

Hazardous.
EPG -
UN Number - 3082
CAS number - Trifloxystrobin 141517-21-7 . Tebuconazole 107534-96-3

ADG (Land)
UN-Number: 3082
Class: 9
Subsidiary Risk: None
Packaging group: III
Description of the goods: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(TEBUCONAZOL, TRIFLOXYSTROBIN SOLUTION)
Hazchem Code: 3Z
According to AU01, Environmentally Hazardous Substances in packagings, IBC or any other receptacle not exceeding 500 kg or 500 L are not subject to the ADG Code.

IMDG (Sea)
UN-Number: 3082
Class: 9
Subsidiary Risk: None
Packaging group: III
EmS: F-A , S-F
Marine pollutant: YES
Description of the goods: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(TEBUCONAZOL, TRIFLOXYSTROBIN SOLUTION)

IATA (Air)
UN-Number: 3082
Class: 9
Subsidiary Risk: None
Packaging group: III
Environm. Hazardous Mark: YES
Description of the goods: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(TEBUCONAZOL, TRIFLOXYSTROBIN SOLUTION )

Risk Phrases: R20, R43, R63, R51/53. Harmful by inhalation. May cause sensitisation by skin contact. Possible risk of harm to the unborn child. Toxic to aquatic organisms, may cause long-term adverse effects to the aquatic environment.
Safety Phrases: S2, S13, S26, S28, S38, S61, S20/21, S36/37/39. Keep out of reach of children. Keep away from food, drink and animal feeding stuffs. In case of contact with eyes, rinse immediately with plenty of water and contact a doctor or Poisons Information Centre. After contact with skin, wash immediately with plenty of soap and water. In
case of insufficient ventilation, wear suitable respiratory equipment. Avoid release to the environment. Refer to special instructions/Safety Data Sheets. When using, do not eat, drink or smoke. Wear suitable protective clothing, gloves and eye/face protection.

32. References:

2104 label & MSDS

Acknowledgments:

Collated by HerbiGuide. Phone 08 98444064 or www.HerbiGuide.com.au for more information.