Triadimenol 250

1. Trade Name 2. Manufacturer3. Formulation
4FARMERS TRIADIMENOL 250 EC FUNGICIDE4 FARMERS PTY LTDEC
BAYFIDAN 250 EC FUNGICIDEBAYER CROPSCIENCE PTY LTDEC
BAYFIDAN TURF FUNGICIDEBAYER CROPSCIENCE PTY LTDEC
CAMPBELL TRIDIM 250 EC FUNGICIDECOLIN CAMPBELL (CHEMICALS) PTY LTDEC
FARMOZ CITADEL FUNGICIDEFARMOZ PTY LIMITEDEC
SHAVIT 250 EC FUNGICIDEMAKHTESHIM-AGAN (AUSTRALIA) PTY LIMITEDEC

4. ACTIVE INGREDIENTS: Triadimenol 250g/L

5. COST: $130.00 per L or kg.

6. CHEMICAL GROUP: C.

7. RELATED PESTICIDES:

Cyproconazole 100 g/L
Cyproconazole 80g/L + propiconazole 250g/L
Epoxiconazole 125g/L
Epoxiconazole 75g/L
Fenarimol 120g/L
Fluquinconazole 167g/L
Flusilazole 200g/kg
Flutriafol 250g/L
Hexaconazole 50 g/L
Imazalil 800g/L
Myclobutanil 200g/L
Propiconazole 250g/L
Tebuconazole 430g/L
Triadimefon 125g/L or 500g/kg
Triadimenol 250g/L
Triforine 190g/L


8. GENERAL DESCRIPTION:

A broad spectrum, systemic agricultural fungicide from the DMI group.

9. APPLICATION METHODS AND TIPS:

High volume, low volume and boom foliar application.

Ensure thorough even coverage.

10. ADJUVANTS, WETTERS, OILS:

Use a non ionic wetting agent on hard to wet crops.

11. EQUIPMENT:

Use equipment that provides thorough even coverage.

12. SPRAYER WASH OUT AND DECONTAMINATION:

Triple rinse with water and wetting agent.

13. WATER OR CARRIER DATA:

250-2000 L/ha.

14. WEATHER:

Apply in fine weather.

15. RAINFASTNESS:

16. SOIL:

No significant effects on performance.

It takes longer to break down in heavier soils.

17. PLANT HEALTH and OTHER EFFECTS:

18. WITHHOLDING PERIODS:

Brassica vegetables: Cutting and grazing - Not required when used as directed

Brassica vegetables: Harvest - 7 Day

Cucurbits: Harvest - 1 Day

Grapevines: Harvest - 7 Day

Papaws: Harvest - 7 Day

Brassica vegetables: Cutting and grazing - Not required when used as directed

Brassica vegetables: Harvest - 7 Day

Cucurbits: Harvest - 1 Day

Grapevines: Harvest - 7 Day

Papaws: Harvest - 7 Day

19. PLANT BACK PERIODS or RECROPPING INTERVALS:

Not applicable

20. MODE OF ACTION:

Systemic. Broad spectrum.

Quickly absorbed by plants resulting it being more robust under rainy or irrigated conditions than contact fungicides.

DMI azole group.

Inhibits ergosterol synthesis.

Protective, curative and eradicant action.

21. PESTICIDE RESISTANCE:

Some species may be resistant or develop resistance with continued application. Rotate with products from alternative groups.

22. TOXICITY:

Poison schedule - S6

Summary:

Details:

Poison schedule - S

Mammalian toxicity -

Acute oral LD50 - 1720-3700 mg/kg (rats), [For comparison table salt is 3000 mg/kg]

Acute dermal LD50 - > 5000 mg/kg (rabbit).

Skin - Irritating. Non sensitising. Can be absorbed through skin. Redness and dermatitis may result from prolonged contact.

Eye - Irritating. May cause temporary corneal clouding.

Vapour inhalation - LC50 - > 0.412 mg/L air (rat). May be harmful if inhaled and produce respiratory irritation.

Chronic oral toxicity NOEL - ppm for two years.

Not mutagenic or teratogenic (i.e. does not cause cancer or reproductive problems).

Acceptable Daily Intake (ADI) -

23. TOXICITY SYMPTOMS:

Nausea and vomiting.

24. FIRST AID:

If SWALLOWED - Rinse mouth with water and give a glass of water to drink. Do NOT induce vomiting. See a doctor. Harmful if swallowed.

If in EYES - Irrigate for 15 minutes with plenty of water. See a doctor. May cause temporary corneal clouding.

If on SKIN - Rinse with plenty of water, remove contaminated clothing, wash with soap and water.

If INHALED - Remove patient to fresh air.

If patient has symptoms or is concerned contact a doctor immediately.

Advice to doctor - Treat symptomatically. Triadimenol is a triazole compound. Symptoms of poisoning have not been recorded.

The solvent N-methyl-2-pyrrolidone causes gastric disturbances such as nausea and vomiting. Treat symptoms.

Call Poisons Information Centre on 13 11 26

25. PROTECTIVE CLOTHING:

Safety goggles and face shield.

Elbow length PVC gloves.

Cotton overalls and washable hat.

Boots.

Wear a respirator for organic solvents if exposed to mist and vapours or where ventilation is poor.

26 RE ENTRY PERIODS and OTHER SAFETY ISSUES:

None specified.

27. PROPERTIES:

Product appearance - Light brown clear liquid with an aromatic odour.

Shelf Life -

Product Flammability - Combustible liquid. Flashpoint 93 (61-150)C. Can emit toxic fumes in fires.

Explosive limits - solvent N-methyl-2-pyrrolidone 1.3-9.5 vol %.

Auto ignition temperature - solvent N-methyl-2-pyrrolidone 245C

Half life in water - days at pH5 and 35 C.

Water solubility at 25 C. - emulsifies in water.

Oil solubility - soluble.

Octanol:Water ratio at 25 C. - Triadimenol LogPow = 3.08 - 3.28 at 25C. Solvent N-methyl-2-pyrrolidone Log Pow = -0.46.

Vapour Pressure at 20 C. - 1hPa. Vapour density 3.4.

Dissociation constant - pKa.

Melting point - C.

Boiling point -

Molecular weight -

Density - SG = 1.09.

pH 6-8 at 1% in water.

28. ENVIRONMENTAL FATE:

Summary - Harmful to aquatic organisms.

Birds - Low toxicity. LD50 >2000 mg/kg.

Fish - toxicity LC50 42-79 mg/L.

Invertebrates - LC50 253 mg/L.

Algae - IC50 41.13 mg/L (72 hr)

Bacteria - EC50 >10,000 mg/L

Bees - Non toxic.

It has a half life in soil of 110-375 days in sandy loam and 240-270 days in loam.

It has an EPA classification for soil mobility that ranges from

Ground water contamination

Accumulation in milk and tissues.

29. COMPATIBILITY:

See HerbiGuide for compatability with other herbicides, insecticides and fungicides.

See HerbiGuide for a full list of pesticide compatibilities.

Compatible with non ionic surfactants (Agridex), White oil, spray oils, sodium molybdate. Baythroid(Cyfluthrin), Morestan(Oxythioquinox)

Not compatible with strong acids or bases and undergoes and exothermic reaction.

30. REGISTERED CROPS, INSECTS and DISEASES.

See Herbiguide Species Solutions Tab for registered uses.

31. GOVERNMENT AND REGULATORY INFORMATION:

Dangerous Goods Class - Not classified as a dangerous good.

Hazchem Code - Not applicable.

Packaging Group - Not applicable.

EPG - Not applicable.

UN Number - Not applicable.

Worksafe Classification -

32. References:

Bayer (2003) Bayfidan Label 30515

Acknowledgments:

Collated by HerbiGuide. Phone 08 98444064 for more information.